Redox-Neutral Rhodium-Catalyzed C-H Functionalization of Arylamine N-Oxides with Diazo Compounds: Primary C(sp3)-H/C(sp2)-H Activation and Oxygen-Atom Transfer

Angewandte Chemie - International Edition

Volumn 54, Issue 41, 2015, Pages 12121-12126

  Zhou, Bing ^a   Chen, Zhaoqiang ^a   Yang, Yaxi ^a   Ai, Wen ^a   Tang, Huanyu ^a   Wu, Yunxiang ^a   Zhu, Weiliang ^a   Li, Yuanchao ^a  

^a SHANGHAI INSTITUTE OF MATERIA MEDICA   (China)

Author keywords

C H activation; density functional calculations; heterocycles; nitrogen oxides; rhodium

Indexed keywords

ACTIVATION ANALYSIS; CATALYSIS; CHEMICAL ACTIVATION; DENSITY FUNCTIONAL THEORY; NITROGEN OXIDES; OXIDANTS; RHODIUM;

ANNULATION REACTIONS; C-H ACTIVATION; C-H FUNCTIONALIZATION; CATALYZED COUPLING; HETEROCYCLES; MILD REACTION CONDITIONS; OXYGEN ATOM TRANSFER; RHODIUM-CATALYZED;

RHODIUM COMPOUNDS;

1 NAPHTHYLAMINE; ANILINE DERIVATIVE; AZO COMPOUND; HYDROGEN; INDOLE DERIVATIVE; INDOLINE; MALONIC ACID DERIVATIVE; MANDELIC ACID DERIVATIVE; NITROGEN OXIDE; RHODIUM;

AMINATION; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION; SYNTHESIS;

1-NAPHTHYLAMINE; AMINATION; ANILINE COMPOUNDS; AZO COMPOUNDS; CATALYSIS; HYDROGEN; INDOLES; MALONATES; MANDELIC ACIDS; MODELS, MOLECULAR; NITROGEN OXIDES; OXIDATION-REDUCTION; RHODIUM;

EID: 84942835741     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201505302     Document Type: Article

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