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Compound 5 was obtained even in the reaction without substrate 2 a under the standard conditions, thus suggesting that DMF could independently react with the Togni reagent under basic conditions
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Compound 5 was obtained even in the reaction without substrate 2 a under the standard conditions, thus suggesting that DMF could independently react with the Togni reagent under basic conditions.
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The nature of the active species in the present reactions is not clear. Nevado proposed that Togni reagent was activated by coordination of an iodide ion, see Ref. [17b]
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