Enantioselective functionalization of radical intermediates in redox catalysis: Copper-catalyzed asymmetric oxytrifluoromethylation of alkenes

Angewandte Chemie - International Edition

Volumn 52, Issue 48, 2013, Pages 12655-12658

  Zhu, Rong ^a   Buchwald, Stephen L ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

asymmetric catalysis; copper; enantioselectivity; radicals; synthetic methods

Indexed keywords

ASYMMETRIC CATALYSIS; ENANTIOSELECTIVE; FUNCTIONALIZATIONS; MECHANISTIC STUDIES; RADICAL ADDITION; RADICALS; SYNTHETIC METHODS; TRIFLUOROMETHYL RADICAL;

COPPER; ENANTIOSELECTIVITY; HYDROCARBONS;

CATALYSIS;

ALKENE; COPPER;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CHEMISTRY; ENANTIOSELECTIVITY; HALOGENATION; METHYLATION; OXIDATION REDUCTION REACTION; RADICALS; STEREOISOMERISM; SYNTHETIC METHODS;

ASYMMETRIC CATALYSIS; COPPER; ENANTIOSELECTIVITY; RADICALS; SYNTHETIC METHODS;

ALKENES; CATALYSIS; COPPER; HALOGENATION; METHYLATION; OXIDATION-REDUCTION; STEREOISOMERISM;

EID: 84887867283     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201307790     Document Type: Article

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