Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity

Journal of the American Chemical Society

Volumn 137, Issue 26, 2015, Pages 8633-8643

  Larsen, Matthew A ^a   Wilson, Conner V ^a   Hartwig, John F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARRIER CONCENTRATION; CATALYSIS; CATALYSTS; ELECTRON DENSITY MEASUREMENT; ELECTRONS; ESTERIFICATION; ESTERS; KINETICS;

CATALYTIC PROCESS; COMPUTATIONAL STUDIES; DIRECTING GROUPS; ELECTRON-DEFICIENT; IRIDIUM CATALYST; MECHANISTIC STUDIES; ORGANIC SYNTHESIS; REDUCTIVE ELIMINATION;

IRIDIUM;

BENZYL DERIVATIVE; BORANE DERIVATIVE; BORONIC ACID DERIVATIVE; CARBON; ESTER; HYDROGEN; IRIDIUM; LIGAND; PHENANTHROLINE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; REAGENT;

ADDITION REACTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; ELECTRON; ELIMINATION REACTION; HYDROBORATION; HYDROGEN BOND; ISOMERIZATION; OXIDATION; SYNTHESIS; TURNOVER TIME;

EID: 84936806439     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b04899     Document Type: Article

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