Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen

Journal of the American Chemical Society

Volumn 136, Issue 24, 2014, Pages 8755-8765

  Li, Qian ^a   Liskey, Carl W ^b   Hartwig, John F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN BONDS; NITROGEN; OXYGEN; REGIOSELECTIVITY;

C-H BOND CLEAVAGE; COMPUTATIONAL RESULTS; HYDROGEN BONDING INTERACTIONS; OXYGEN AND NITROGENS; RATE DETERMINING STEP; STABILIZING INTERACTIONS; STERIC INTERACTIONS; SUZUKI-MIYAURA CROSS-COUPLING REACTION;

ETHERS;

ALKYL ETHER; ARALKYLAMINE; ETHYLAMINE; LEWIS ACID; LEWIS BASE; LIGAND; NITROGEN; OXYGEN;

ARTICLE; BORYLATION; CHEMICAL INTERACTION; CHEMICAL REACTION; HYDROGEN BOND; MOLECULAR STABILITY; REACTION ANALYSIS; STEREOCHEMISTRY; SUZUKI REACTION;

EID: 84902669885     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja503676d     Document Type: Article

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