Getting the sterics just right: A five-coordinate iridium trisboryl complex that reacts with C-H bonds at room temperature

Chemical Communications

Volumn , Issue 38, 2009, Pages 5731-5733

  Chotana, Ghayoor A ^a   Vanchura II, Britt A ^a   Tse, Man Kin ^a   Staples, Richard J ^a   Maleczka Jr , Robert E ^a   Smith III, Milton R ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM COMPLEX; IRIDIUM TRISBORYL COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COVALENT BOND; CRYSTAL STRUCTURE; HYDROGEN BOND; ROOM TEMPERATURE; STEREOCHEMISTRY; SYNTHESIS;

EID: 70349318576     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b914736e     Document Type: Article

References (17)

1. J. Y. Cho M. K. Tse D. Holmes R. E. Maleczka, Jr M. R. Smith, III Science 2002 295 305 308
2. T. Ishiyama J. Takagi K. Ishida N. Miyaura N. R. Anastasi J. F. Hartwig J. Am. Chem. Soc. 2002 124 390 391
3. J. Halpern Science 1982 217 401 407
4. We previously outlined this strategy for preparing 5-coordinate boryl complexes: G. A. Chotana, R. E. Maleczka, Jr and M. R. Smith, III, Abstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007, 2007, INOR-188
5. W. Clegg F. J. Lawlor T. B. Marder P. Nguyen N. C. Norman A. G. Orpen M. J. Quayle C. R. Rice E. G. Robins A. J. Scott F. E. S. Souza G. Stringer G. R. Whittell J. Chem. Soc., Dalton Trans. 1998 301 309
6. G. J. Kubas, Metal Dihydrogen and Sigma-Bond Complexes: Structure, Theory, and Reactivity, Kluwer Academic/Plenum Publishers, New York, 2001
7. Y. K. Sau H. K. Lee I. D. Williams W. H. Leung Chem.-Eur. J. 2006 12 9323 9335
8. N. M. Scott V. Pons E. D. Stevens D. M. Heinekey S. P. Nolan Angew. Chem., Int. Ed. 2005 44 2512 2515
9. E. Clot J. Y. Chen D. H. Lee S. Y. Sung L. N. Appelhans J. W. Faller R. H. Crabtree O. Eisenstein J. Am. Chem. Soc. 2004 126 8795 8804
10. R. Dorta R. Goikhman D. Milstein Organometallics 2003 22 2806 2809
11. E. Clot O. Eisenstein T. Dube J. W. Faller R. H. Crabtree Organometallics 2002 21 575 580
12. A. C. Cooper W. E. Streib O. Eisenstein K. G. Caulton J. Am. Chem. Soc. 1997 119 9069 9070
13. J. Takagi K. Sato J. F. Hartwig T. Ishiyama N. Miyaura Tetrahedron Lett. 2002 43 5649 5651
14. 4BPin can be seen in the milieu. These have been fully characterized and details will be published in due course. Some of these findings have been publicly disseminated. See: B. A. Vanchura, B. Ramanathan, G. A. Chotana and M. R. Smith III, Abstracts of Papers, 237th ACS National Meeting, Salt Lake City, UT, United States, March 22-26, 2009, 2009, INOR-001
15. H. Tamura H. Yamazaki H. Sato S. Sakaki J. Am. Chem. Soc. 2003 125 16114 16126
16. D. A. Singleton and M. R. Smith, III, manuscript in preparation
17. C. W. Liskey C. S. Wei D. R. Pahls J. F. Hartwig Chem. Commun. 2009 10.1039/b913949d