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Volumn 51, Issue 41, 2015, Pages 8699-8701

Silver(I) NHC mediated C-C bond activation of alkyl nitriles and catalytic efficiency in oxazoline synthesis

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE; CARBON; N HETEROCYCLIC CARBENE; NITRILE; OXAZOLINE DERIVATIVE; SILVER; UNCLASSIFIED DRUG;

EID: 84929223080     PISSN: 13597345     EISSN: 1364548X     Source Type: Journal    
DOI: 10.1039/c5cc02558c     Document Type: Article
Times cited : (34)

References (49)
  • 16
    • 84929200136 scopus 로고    scopus 로고
    • note
    • CCDC 1044757 (2a/2b co-crystal) and 1044758 (pure 2a).
  • 25
    • 84929200137 scopus 로고    scopus 로고
    • note
    • 3CN or when PhCN is used as solvent.
  • 31
    • 84929200138 scopus 로고    scopus 로고
    • note
    • Postmodification through metathesis of [AgI(trz)] and Ag(CN) can be excluded because of the high ratio of [Ag(CN)(trz)] formed in the reaction (>80%) and the inertness of Ag(CN) to activate the trz-H bond. The observed traces of 2b more likely result from a metathesis of 2a with AgI.
  • 32
    • 84929200139 scopus 로고    scopus 로고
    • note
    • This model assumes irreversible reaction of trz-Ag-OH with iodide, which is supported by the absence of any traces of silver hydroxide.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.