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Volumn 26, Issue 10, 2007, Pages 2679-2687

Metalloradical activations of aliphatic carbon-carbon bonds of nitriles: Scope and mechanism

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; CHEMICAL ACTIVATION; CHEMICAL BONDS; LIGANDS; ORGANOMETALLICS; REACTION KINETICS; RHODIUM COMPOUNDS;

EID: 34249079359     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om070064j     Document Type: Article
Times cited : (26)

References (69)
  • 30
    • 37049067890 scopus 로고    scopus 로고
    • Del, Rossi, K. J.; Wayland, B. B. J. Chem. Soc., Chem. Commun. 1986, 1653-1655.
    • (d) Del, Rossi, K. J.; Wayland, B. B. J. Chem. Soc., Chem. Commun. 1986, 1653-1655.
  • 34
    • 0035820129 scopus 로고    scopus 로고
    • Carbon-carbon bond activation occurred only at 70°C in 4 h, but not at room temperature. See: Tse, M. K.; Chan, K. S. J. Chem. Soc., Dalton Trans. 2001, 510-511.
    • (h) Carbon-carbon bond activation occurred only at 70°C in 4 h, but not at room temperature. See: Tse, M. K.; Chan, K. S. J. Chem. Soc., Dalton Trans. 2001, 510-511.
  • 40
    • 0000429083 scopus 로고    scopus 로고
    • Formation of the Rh(tmp)-ligand 1:1 complex has been reported, (a) Wayland, B. B.; Sherry, A. E. Bunn, A. G. J. Am. Chem. Soc. 1993, 115, 7675-7684.
    • Formation of the Rh(tmp)-ligand 1:1 complex has been reported, (a) Wayland, B. B.; Sherry, A. E. Bunn, A. G. J. Am. Chem. Soc. 1993, 115, 7675-7684.
  • 43
    • 0000617013 scopus 로고
    • Kochi, J. K, Ed, Wiley: New York
    • (b) Davis, A. G.; Roberts, B. P. Free Radicals; Kochi, J. K., Ed.; Wiley: New York, 1973; Vol. 2, pp 547-589.
    • (1973) Free Radicals , vol.2 , pp. 547-589
    • Davis, A.G.1    Roberts, B.P.2
  • 60
    • 34249095172 scopus 로고    scopus 로고
    • The kinetic order of Rh(tmp) was preliminarily estimated from the first-order fit of the absorbance change. We did not pursue investigating the kinetic order of Ph3P, i.e, n in eq 13
    • 3P, i.e., n in eq 13.
  • 63
    • 34249017990 scopus 로고    scopus 로고
    • 2CN is likely sterically hindered. See also: Hetterscheid, D. G. H.; Bens, M.; de Bruin, B. Dalton Trans. 2005, 979-984.
    • 2CN is likely sterically hindered. See also: Hetterscheid, D. G. H.; Bens, M.; de Bruin, B. Dalton Trans. 2005, 979-984.
  • 65
    • 0000617013 scopus 로고
    • Kochi, J. K, Ed, Wiley: New York
    • (b) Davis, A. G.; Roberts, B. P. Free Radicals; Kochi, J. K., Ed.; Wiley: New York, 1973; Vol. 2, pp 547-589.
    • (1973) Free Radicals , vol.2 , pp. 547-589
    • Davis, A.G.1    Roberts, B.P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.