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Volumn 34, Issue 7, 2015, Pages 1384-1395

Synthesis and Characterization of N-Trifluoromethyl N-Heterocyclic Carbene Ligands and Their Complexes

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CHELATION; CHLORINE COMPOUNDS; GOLD COMPOUNDS; IRIDIUM; NUCLEAR MAGNETIC RESONANCE; ORGANIC COMPOUNDS; REDOX REACTIONS; RHODIUM; RHODIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

EID: 84927743877     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/acs.organomet.5b00137     Document Type: Article
Times cited : (44)

References (58)
  • 28
    • 84927762781 scopus 로고    scopus 로고
    • note
    • The average CO stretching frequency of [IrCl(CO)2(NHC)] complexes νav(CO) can be related to the TEP parameter by the following equation: TEP = 0.847 × νav(CO) + 336 cm-1. For the derivation of this equation, see ref 15a.
  • 31
    • 84927762780 scopus 로고    scopus 로고
    • note
    • For the derivation of the equation, see ref 15a.
  • 38
    • 84927762779 scopus 로고    scopus 로고
    • note
    • See refs 9b and 9c.
  • 40
    • 84927762778 scopus 로고    scopus 로고
    • note
    • Reaction conditions: 10 (0.25 mmol), 11 (2.5 mmol), gold complex (0.0125 mmol), and AgNTf2 (0.0125 mol) in PhCl (0.25 mL) for 20 h. Yields were determined by GC analysis, using n -tetradecane as an internal standard. See ref 9b.
  • 52
    • 84927762777 scopus 로고    scopus 로고
    • note
    • For the synthesis of [Au(IDNP)Cl], see ref 9c.
  • 55
    • 84927762776 scopus 로고    scopus 로고
    • note
    • For quaternization of N-substitueted imidazoles by diaryliodonium salts, see ref 14.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.