Phosphine-catalyzed remote β-C-H functionalization of amines triggered by trifluoromethylation of alkenes: One-pot synthesis of bistrifluoromethylated enamides and oxazoles

Angewandte Chemie - International Edition

Volumn 54, Issue 13, 2015, Pages 4041-4045

  Yu, Peng ^a   Zheng, Sheng Cai ^a   Yang, Ning Yuan ^a   Tan, Bin ^a   Liu, Xin Yuan ^a  

^a SOUTHERN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

1,5 H radical shift; alkenes; radical chemistry; trifluoromethylation; C H functionalization

Indexed keywords

CATALYSIS; OLEFINS; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL);

1,5-H RADICAL SHIFT; AMINE DERIVATIVES; C-H FUNCTIONALIZATION; MECHANISTIC STUDIES; ONE-POT PROTOCOL; ONE-POT SYNTHESIS; RADICAL CHEMISTRY; TRIFLUOROMETHYLATION; FUNCTIONALIZATIONS;

HYDROCARBONS; OLEFINS;

ALKENE; AMIDE; AMINE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; FLUOROCARBON; OXAZOLE DERIVATIVE; PHOSPHINE; PHOSPHINE DERIVATIVE;

CATALYSIS; CHEMISTRY; SYNTHESIS;

ALKENES; AMIDES; AMINES; CATALYSIS; FLUOROCARBON POLYMERS; INDICATORS AND REAGENTS; OXAZOLES; PHOSPHINES;

EID: 84924905328     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201412310     Document Type: Article

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