Copper-catalyzed aminotrifluoromethylation of unactivated alkenes with (TMS)CF3: Construction of trifluoromethylated azaheterocycles

Journal of Organic Chemistry

Volumn 79, Issue 15, 2014, Pages 7084-7092

  Lin, Jin Shun ^a   Liu, Xiang Geng ^a   Zhu, Xiao Long ^a   Tan, Bin ^a   Liu, Xin Yuan ^a  

^a SOUTHERN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; OLEFINS;

AZA-HETEROCYCLES; COPPER CATALYZED; MECHANISTIC STUDIES; PLAUSIBLE MECHANISMS; SIX-MEMBERED RINGS; TRIFLUOROMETHYL; TRIMETHYL;

COPPER COMPOUNDS;

ALKENE DERIVATIVE; AZIRIDINE DERIVATIVE; CUPROUS ION; HETEROCYCLIC COMPOUND; SILANE DERIVATIVE; TRANSITION ELEMENT; UNCLASSIFIED DRUG; [TRIMETHYL(TRIFLUOROMETHYL)SILANE]; ALKENE; COPPER; FLUORINATED HYDROCARBON; TRIMETHYLSILYL DERIVATIVE;

AMINOTRIFLUOROMETHYLATION; ARTICLE; CATALYSIS; CONTROLLED STUDY; ELECTRON TRANSPORT; ELECTROPHILICITY; FLUORINE NUCLEAR MAGNETIC RESONANCE; MASS SPECTROMETRY; METHYLATION; NUCLEOPHILICITY; PROTON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALKENES; CATALYSIS; COPPER; HETEROCYCLIC COMPOUNDS; HYDROCARBONS, FLUORINATED; MOLECULAR STRUCTURE; STEREOISOMERISM; TRIMETHYLSILYL COMPOUNDS;

EID: 84905372529     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo5012619     Document Type: Article

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