N-heterocyclic carbene catalyzed switchable reactions of enals with azoalkenes: Formal [4 + 3] and [4 + 1] annulations for the synthesis of 1,2-diazepines and pyrazoles

Journal of the American Chemical Society

Volumn 136, Issue 50, 2014, Pages 17402-17405

  Guo, Chang ^a   Sahoo, Basudev ^a   Daniliuc, Constantin G ^a   Glorius, Frank ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; ENANTIOSELECTIVITY; ORGANIC COMPOUNDS;

ANNULATION REACTIONS; ENANTIOSELECTIVE; FUNCTIONALIZED; N-HETEROCYCLIC CARBENES; ORGANOCATALYSTS; PYRAZOLE DERIVATIVES; REACTION PATHWAYS; STERIC PROPERTIES;

SYNTHESIS (CHEMICAL);

CARBENE; DIAZEPINE DERIVATIVE; PYRAZOLE DERIVATIVE;

ANNULATION REACTION; ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; ENANTIOSELECTIVITY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SYNTHESIS;

EID: 84919335951     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja510737n     Document Type: Article

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