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Volumn 5, Issue 1, 2015, Pages 124-128

Catalytic enantioselective synthesis of α-nitroepoxides via aminolytic kinetic resolution

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; ENANTIOSELECTIVITY;

EID: 84916210431     PISSN: 20444753     EISSN: 20444761     Source Type: Journal    
DOI: 10.1039/c4cy01157k     Document Type: Article
Times cited : (14)

References (69)
  • 7
    • 0000345527 scopus 로고    scopus 로고
    • ed. E. N. Jacobsen, A. Pfaltz and H. Yamamoto, Springer, Berlin
    • (a) T. Katsuki, in Comprehensive Asymmetric Catalysis, ed. E. N. Jacobsen, A. Pfaltz and H. Yamamoto, Springer, Berlin, 1999, p. 621;
    • (1999) Comprehensive Asymmetric Catalysis , pp. 621
    • Katsuki, T.1
  • 38
    • 84902416890 scopus 로고    scopus 로고
    • ed. E. M. Carreira and H. Yamamoto, Elsevier, Oxford
    • (a) J. F. Larrow and P. F. Quigley in Comprehensive Chirality, ed. E. M. Carreira and H. Yamamoto, Elsevier, Oxford, 2012, p. 129.
    • (2012) Comprehensive Chirality , pp. 129
    • Larrow, J.F.1    Quigley, P.F.2
  • 53
    • 84916225225 scopus 로고    scopus 로고
    • note
    • An excess of aniline (1.2 equiv.) was added to neutralize nitrous acid formed as by-product.
  • 56
    • 84916209600 scopus 로고    scopus 로고
    • note
    • Other unidentified products were observed in the crude reaction mixture.
  • 57
    • 84916207553 scopus 로고    scopus 로고
    • note
    • First order kinetics was assumed for the calculation of the stereoselectivity factors, 11 a which are underestimated because partially affected by contribution of the background ring-opening reaction.
  • 58
    • 84916212897 scopus 로고    scopus 로고
    • note
    • As an example, innodataalpha -amino ketone 3a, reported in entry 1 of Table 3, was recovered with 16% ee.
  • 64
    • 84916244362 scopus 로고    scopus 로고
    • note
    • The ring-opening/reduction sequence was not optimized.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.