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Volumn 12, Issue 31, 2014, Pages 5847-5855

Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: A new powerful strategy for the synthesis of highly congested chiral cyclohexenones

Author keywords

[No Author keywords available]

Indexed keywords

KETONES;

EID: 84904445433     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/c4ob00733f     Document Type: Article
Times cited : (40)

References (75)
  • 36
  • 71
    • 0344681662 scopus 로고
    • We believe that high pressure can accelerate both the catalyst-substrate interactions and C-C bond-forming reactions. For a review on organocatalytic reactions at high pressure, see
    • M. S. Newman A. G. Pinkus J. Org. Chem. 1954 19 978
    • (1954) J. Org. Chem. , vol.19 , pp. 978
    • Newman, M.S.1    Pinkus, A.G.2
  • 74
    • 0004018410 scopus 로고    scopus 로고
    • Wiley-VCH, Weinheim, We did not check the use of 20 mol% of catalyst Although we did not check other carbon nucleophiles, the process should be also applicable to acetylacetone and related compounds. See ref. 12 The low yield in this step is due to the formation of complex by-products
    • C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, Wiley-VCH, Weinheim, 2003
    • (2003) Solvents and Solvent Effects in Organic Chemistry
    • Reichardt, C.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.