An alternative RP-HPLC method for the separation and determination of tocopherol and tocotrienol homologues as butter authenticity markers: A comparative study between two European countries

European Journal of Lipid Science and Technology

Volumn 116, Issue 7, 2014, Pages 895-903

  Górnaś, Pawel ^a   Siger, Aleksander ^b   Czubinski, Jaroslaw ^b   Dwiecki, Krzysztof ^b   Segliņa, Dalija ^a   Nogala Kalucka, Malgorzata ^b  

^a Latvia University of Life Sciences and Technologies   (Latvia)

^b POZNA UNIVERSITY OF LIFE SCIENCES   (Poland)

Author keywords

Authentication of butter; NP HPLC; RP HPLC; Tocopherols; Tocotrienols

Indexed keywords

EID: 84903814407     PISSN: 14387697     EISSN: 14389312     Source Type: Journal    
DOI: 10.1002/ejlt.201300319     Document Type: Article

References (27)

1. EEC Council Regulation No. 2991/94 laying down standards for spreadable fats. Off. J. Eur. Communities No. L316, 9.12.94.
2. EEC Council Regulation No. 1898/87 on the protection of designations used in the marketing of milk and milk products. Off. J. Eur. Communities No. L182, 3.7.87.
3. Fearon, A. M., Golding, M., in: Chandan, R. C., Kilara, A., Shah, N. P. (Eds.), Dairy Processing and Quality Assurance, Wiley-Blackwell, Oxford, UK 2008, pp. 253-272.
4. Bosque-Sendra, J. M., Cuadros-Rodríguez, L., Ruiz-Samblás, C., de la Mata, A. P., Combining chromatography and chemometrics for the characterization and authentication of fats and oils from triacylglycerol compositional data - A review. Anal. Chim. Acta 2012, 724, 1-11.
5. Derewiaka, D., Sosińska, E., Obiedziński, M., Krogulec, A., Czaplicki, S., Determination of the adulteration of butter. Eur. J. Lipid Sci. Technol. 2011, 113, 1005-1011.
6. Dwiecki, K., Górnaś, P., Jackowiak, H., Nogala-Kalucka, M., Polewski, K., The effect of d-alpha-tocopherol on the solubilization of dipalmitoylphosphatidylcholine membrane by anionic detergent sodium dodecyl sulfate. J. Food Lipids, 2007, 14, 50-61.
7. Dwiecki, K., Górnaś, P., Wilk, A., Nogala-Kalucka, M., Polewski, K., Spectroscopic studies of d-α-tocopherol concentration-induced transformation in egg phospatydilocholine vesicles. Cell. Mol. Biol. Lett. 2007, 12, 51-69.
8. Górnaś, P., Siger, A., Segliņa, D., Physicochemical characteristics of the cold-pressed Japanese quince seed oil: New promising unconventional bio-oil from by-products for the pharmaceutical and cosmetic industry. Ind. Crop. Prod. 2013, 48, 178-182.
9. Grebenstein, N., Frank, J., Rapid baseline-separation of all eight tocopherols and tocotrienols by reversed-phase liquid-chromatography with a solid-core pentafluorophenyl column and their sensitive quantification in plasma and liver. J. Chromatogr. A 2012, 1243, 39-46.
10. Inoue, T., Tatemori, S., Muranaka, N., Hirahara, Y. et al., The identification of vitamin E homologues in medicinal plant samples using ESI(+)-LC-MS3. J. Agric. Food Chem. 2012, 60, 9581-9588.
11. Cert, A., Moreda, W., Pérez-Camino, M. C., Chromatographic analysis of minor constituents in vegetable oils. J. Chromatogr. A 2000, 881, 131-148.
12. Irakli, M. N., Samanidou, V. F., Papadoyannis, I. N., Optimization and validation of the reversed-phase high-performance liquid chromatography with fluorescence detection method for the separation of tocopherol and tocotrienol isomers in cereals, Employing a Novel Sorbent Material. J. Agric. Food Chem. 2012, 60, 2076-2082.
13. Snyder, L. R., Kirkland, J. J., Dolan, J. W., Introduction to Modern Liquid Chromatography, John Wiley & Sons, Hoboken, New Jersey 2010.
14. Siger, A., Kachlicki, P., Czubiński, J., Polcyn, D. et al., Isolation and purification of plastochromanol-8 for HPLC quantitative determinations. Eur. J. Lipids Sci. Technol. 2014, 116, DOI: 10.1002/ejlt.201300297.
15. Chowa, C. K., in: Rucker, R. B., Suttie, J. W., McCormick, D. B., Machlin, L. J. (Eds.), Handbook of Vitamins, Marcel Dekker, New York 2001, pp. 165-198.
16. Stolyhwo, A., Rutkowska, J., in: Food Chemistry, Nutritional and Health Properties of Food Ingredients, Sikorski, Z. E. (Ed.), WNT, Warszawa 2007, pp. 39-89.
17. Ball, G. F. M., Vitamins in Food. Analysis, Bioavailability and Stability, CRC Press, Boca Raton 2006.
18. Delgado Zamarreno, M. M., Sanchez Perez, A., Bustamante Rangel, M., Hernandez Mendez, J., Automated analysis for vitamin E in butter by coupling sample treatment - continuous membrane extraction - liquid chromatography with electrochemical detection. Anal. Chim. Acta 1999, 386, 99-106.
19. Kalač, P., The effects of silage feeding on some sensory and health attributes of cow's milk: A review. Food Chem. 2011, 125, 307-317.
20. Czauderna, M., Kowalczyk, J., Alkaline saponification results in the composition of tocopherols in milk and ovine blood plasma. J. Chromatogr. B 2006, 858, 8-12.
21. Boutrolle, I., Delarue, J., Köster, E., Aranz, D., Danzart, M., Use of a test of perceived authenticity to trigger affective responses when testing food. Food Qual. Prefer. 2009, 20, 418-426.
22. Eitenmiller, R., Lee, J., Vitamin E. Food Chemistry, Composition and Analysis, Marcel Decker Inc., New York 2004.
23. Nogala-Kalucka, M., Pikul, J., Siger, A., Application of liquid chromatography (HPLC) to determine butter autheticity. Żywność. Nauka. Technologia. Jakość 2008, 3, 47-56.
24. Frank, J., Chin, X. W. D., Schrader, Ch., Eckert, G. P., Rimbach, G., Do tocotrienols have potential as neuroprotective dietary factors? Ageing Res. Rev. 2012, 11, 163-180.
25. Przybylski, R., Mag, T., in: Vegetable Oils in Food Technology. Composition, Properties and Uses, Gunstone, F. D. (Eds.), Blackwell Publishing Ltd., Oxford 2002, pp. 98-127.
26. Gawrysiak-Witulska, M., Siger, A., Wawrzyniak, J., Nogala-Kalucka, M., Changes in tocochromanol content in seeds of Brassica napus L. during adverse conditions of storage. J. Am. Oil Chem. Soc. 2011, 88, 1379-1385.
27. Balasubramanian, S., Panigrahi, S., Solid-phase microextraction (SPME) techniques for quality characterization of food products: A review. Food Bioprocess Technol. 2011, 4, 1-26.