Atropisomerism about aryl-csp3 bonds: The electronic and steric influence of ortho -substituents on conformational exchange in cannabidiol and linderatin derivatives

Journal of Organic Chemistry

Volumn 79, Issue 13, 2014, Pages 6015-6027

  Berber, Hatice ^a   Lameiras, Pedro ^a   Denhez, Clément ^a   Antheaume, Cyril ^b   Clayden, Jonathan ^c  

^a UNIVERSITÉ DE REIMS CHAMPAGNE ARDENNE   (France)

^b UNIVERSITÉ DE STRASBOURG   (France)

^c UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY;

CHARGE TRANSFER INTERACTION; CONFORMATIONAL BEHAVIOR; CONFORMATIONAL CHANGE; CONFORMATIONAL CONTROL; CONFORMATIONAL EXCHANGE; ELECTRONIC STABILIZATION; RESTRICTED ROTATIONS; THEORETICAL CALCULATIONS;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CANNABIDIOL DERIVATIVE; LINDERATIN DERIVATIVE; NATURAL PRODUCT; UNCLASSIFIED DRUG; CANNABIDIOL; LINDERATIN; PHENOL DERIVATIVE;

ARTICLE; CALCULATION; CHEMICAL BOND; CONFORMATIONAL TRANSITION; DENSITY FUNCTIONAL THEORY; EPIMER; ISOMERISM; STEREOCHEMISTRY; SYNTHESIS; ANALOGS AND DERIVATIVES; CHEMISTRY; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

CANNABIDIOL; CRYSTALLOGRAPHY, X-RAY; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; PHENOLS; QUANTUM THEORY; STEREOISOMERISM;

EID: 84903716706     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo5006069     Document Type: Article

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