Redox-triggered C-c coupling of alcohols and vinyl epoxides: Diastereo- and enantioselective formation of all-carbon quaternary centers via tert -(Hydroxy)-prenylation

Journal of the American Chemical Society

Volumn 136, Issue 25, 2014, Pages 8911-8914

  Feng, Jiajie ^a   Garza, Victoria J ^a   Krische, Michael J ^a  

^a University of Texas at Austin   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; BYPRODUCTS; ENANTIOSELECTIVITY;

C-C COUPLING; C-O BOND CLEAVAGE; CARBONYL ADDITION; ENANTIOSELECTIVE FORMATION; NATURAL PRODUCTS; PRIMARY ALCOHOLS; QUATERNARY CENTERS; REDOX MANIPULATION;

CARBON;

ALCOHOL; ALCOHOL DERIVATIVE; ALDEHYDE; CARBON; CARBONYL DERIVATIVE; EPOXIDE; IRIDIUM; ISOPRENE; NATURAL PRODUCT; OXYGEN; REAGENT; TERPENOID; VINYL DERIVATIVE; TERPENE;

ALCOHOL OXIDATION; ARTICLE; CATALYSIS; COVALENT BOND; ENANTIOSELECTIVITY; OXIDATION REDUCTION REACTION; PRENYLATION; STOICHIOMETRY; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALCOHOLS; CATALYSIS; EPOXY COMPOUNDS; IRIDIUM; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PRENYLATION; STEREOISOMERISM; TERPENES; VINYL COMPOUNDS;

EID: 84903286968     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja504625m     Document Type: Article

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