Anti-diastereo-and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level employing a cyclometallated iridium catalyst: α-methyl allyl acetate as a surrogate to preformed crotylmetal reagents

Journal of the American Chemical Society

Volumn 131, Issue 7, 2009, Pages 2514-2520

  Kim, In Su ^a   Han, Soo Bong ^a   Krische, Michael J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

[CARBONYL; ALLYL ACETATE; C-C BOND FORMATION; CARBONYL ADDITION; CHIRAL PHOSPHINE; DIASTEREO-SELECTIVITY; ENANTIO; ENANTIOSELECTIVE; IN-SITU; INTERCONVERSION; IRIDIUM CATALYST; ISO-PROPANOL; NITROBENZOIC ACIDS; OXIDATION LEVEL; REDUCTANT; SEGPHOS; TRANSFER HYDROGENATIONS;

ALDEHYDES; AROMATIC HYDROCARBONS; CARBOXYLIC ACIDS; CATALYSIS; CATALYSTS; ENANTIOSELECTIVITY; IONIZATION; IRIDIUM; OXIDATION; PHOSPHORUS COMPOUNDS;

CARBONYLATION;

2 PROPANOL; ALCOHOL DERIVATIVE; ALLYL COMPOUND; ALPHA METHYLALLYL ACETATE; BENZOIC ACID DERIVATIVE; CARBONYL DERIVATIVE; IRIDIUM COMPLEX; PHOSPHINE DERIVATIVE; REDUCING AGENT; UNCLASSIFIED DRUG; ACETIC ACID DERIVATIVE; ALDEHYDE; ALLYL ACETATE; IRIDIUM; NITROBENZOIC ACID DERIVATIVE; ORGANOMETALLIC COMPOUND;

ARTICLE; CATALYST; CHEMICAL REACTION; DIASTEREOISOMER; ENANTIOSELECTIVITY; HYDROGENATION; IONIZATION; OXIDATION REDUCTION REACTION; CATALYSIS; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ACETATES; ALCOHOLS; ALDEHYDES; ALLYL COMPOUNDS; CATALYSIS; HYDROGENATION; IRIDIUM; NITROBENZOATES; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PHOSPHINES; STEREOISOMERISM;

EID: 67749093229     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808857w     Document Type: Article

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