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Volumn 5, Issue 1, 2014, Pages 291-296

Rhodium-catalyzed regioselective opening of vinyl epoxides with Et 3N·3HF reagent-formation of allylic fluorohydrins

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT AIR; ENANTIOPURE; MECHANISTIC STUDIES; REGIO-SELECTIVE; RHODIUM-CATALYZED; RING OPENING; ROOM TEMPERATURE;

EID: 84888592542     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c3sc51949j     Document Type: Article
Times cited : (43)

References (65)
  • 55
    • 84870479877 scopus 로고    scopus 로고
    • There are two examples of regioselective opening of vinyl epoxides with triethylamine trihydrofluoride in the absence of the metal catalyst, see
    • J. Zhu G. C. Tsui M. Lautens Angew. Chem., Int. Ed. 2012 51 12353
    • (2012) Angew. Chem., Int. Ed. , vol.51 , pp. 12353
    • Zhu, J.1    Tsui, G.C.2    Lautens, M.3
  • 57
    • 33845959969 scopus 로고    scopus 로고
    • 2O as a solvent in rhodium-catalyzed ring-opening of vinyl epoxide 1 resulted in a biphasic mixture. This phase separation eliminates the need for an aqueous workup, and the crude product 2A was extracted from a biphasic mixture and subsequently treated with 4-flurobenzoyl chloride to form isolable allylic fluoride 2
    • L. Hunter D. O'Hagan A. M. Z. Sawin J. Am. Chem. Soc. 2006 128 16422 16423
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 16422-16423
    • Hunter, L.1    O'Hagan, D.2    Sawin, A.M.Z.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.