Diastereo- and enantioselective iridium-catalyzed carbonyl propargylation from the alcohol or aldehyde oxidation level: 1,3-enynes as allenylmetal equivalents

Angewandte Chemie - International Edition

Volumn 51, Issue 12, 2012, Pages 2972-2976

  Geary, Laina M ^a   Woo, Sang Kook ^a   Leung, Joyce C ^a   Krische, Michael J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

enantioselectivity; homogeneous catalysis; iridium; propargylation; transfer hydrogenation

Indexed keywords

CARBONYL PROPARGYLATION; CHIRALITY TRANSFER; CONJUGATED ENYNES; ENANTIOSELECTIVE; HOMOGENEOUS CATALYSIS; IRIDIUM CATALYST; OXIDATION LEVEL; PROPARGYLATION; REDUCTANTS; SEGPHOS; TRANSFER HYDROGENATIONS;

ALDEHYDES; ENANTIOMERS; ENANTIOSELECTIVITY; FORMIC ACID; HYDROGENATION; IRIDIUM; REACTION KINETICS;

ORGANIC COMPOUNDS;

EID: 84858166704     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201200239     Document Type: Article

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