Vinylepoxides as versatile substrates for allylations of amino acids and peptides

Synlett

Volumn , Issue 1, 2010, Pages 137-141

  Thies, Sarah ^a   Kazmaier, Uli ^a  

^a SAARLAND UNIVERSITY   (Germany)

Author keywords

Allylic alkylation; Amino acids; Chelates; Epoxides; Palladium

Indexed keywords

AMINO ACID; EPOXIDE; PEPTIDE;

ALKYLATION; ALLYLATION; ARTICLE; CATALYSIS; NUCLEOPHILICITY; SUBSTITUTION REACTION;

EID: 77951692149     PISSN: 09365214     EISSN: 14372096     Source Type: Journal    
DOI: 10.1055/s-0029-1218536     Document Type: Article

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84. 4), the solvent was evaporated in vacuo, and the crude product was purified by flash chromatography (silica gel; hexanes-EtOAc).
85. 3): δ = 169.2, 156.6 (J = 37.9 Hz), 134.5, 124.2, 115.6 (J = 287.6 Hz), 83.6, 62.9, 52.6, 34.6, 28.0.
86. 5: 445.1906; found: 445. 1942.