Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy esters

Journal of the American Chemical Society

Volumn 134, Issue 38, 2012, Pages 15700-15703

  Leung, Joyce C ^a   Geary, Laina M ^a   Chen, Te Yu ^a   Zbieg, Jason R ^a   Krische, Michael J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

C-C COUPLING; C-H BOND; CATALYTIC CYCLES; DIRECT CONVERSION; HYDROXY ESTERS; IN-SITU; MECHANISTIC STUDIES; MYRCENE; OXIDATIVE COUPLINGS; PRENYLATION; RUTHENIUM CATALYSTS; TERTIARY ALCOHOLS;

BYPRODUCTS; COUPLINGS; ESTERIFICATION; ESTERS; METHANOL; REGIOSELECTIVITY; RUTHENIUM;

OLEFINS;

ALKADIENE; ALPAH HYDROXY ESTER DERIVATIVE; CARBON; ESTER DERIVATIVE; METHANOL; PHOSPHINE DERIVATIVE; RUTHENIUM; TRICYCLOHEXYLPHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; GERANYLATION; PRENYLATION;

CATALYSIS; ESTERS; MAGNETIC RESONANCE SPECTROSCOPY; METHANOL; OXIDATION-REDUCTION; PRENYLATION; RUTHENIUM;

EID: 84866719313     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3075049     Document Type: Article

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