Autocatalytic formation of an iron(IV)-oxo complex via scandium ion-promoted radical chain autoxidation of an iron(II) complex with dioxygen and tetraphenylborate

Journal of the American Chemical Society

Volumn 136, Issue 22, 2014, Pages 8042-8049

  Nishida, Yusuke ^a   Lee, Yong Min ^b   Nam, Wonwoo ^b   Fukuzumi, Shunichi ^a,b  

^a OSAKA UNIVERSITY   (Japan)

^b Ewha Womans University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHAINS; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; IONS; IRON; ORGANOMETALLICS; OXIDATION; PORPHYRINS; SCANDIUM; SCANDIUM COMPOUNDS;

ACTIVATION PATHWAY; AUTOCATALYTIC FORMATION; AUTOCATALYTIC OXIDATION; CATALYTIC AMOUNTS; INDUCTION PERIODS; RADICAL CHAIN REACTIONS; SCANDIUM TRIFLATE; TETRAPHENYLBORATES;

IRON COMPOUNDS;

ACETONITRILE; BENZENE DERIVATIVE; BIPHENYL; FERROCENE; FERROUS ION; HYDROPEROXIDE DERIVATIVE; IRON(IV) OXO COMPLEX; OXYGEN; PEROXY RADICAL; PHENOL; RADICAL; SCANDIUM TRIFLATE; TETRAPHENYLBORON; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; FREE RADICAL; IRON; NONHEME IRON PROTEIN; SCANDIUM;

ARTICLE; AUTOOXIDATION; BINDING AFFINITY; CATALYST; COMPLEX FORMATION; DECOMPOSITION; ELECTRON TRANSPORT; ION TRANSPORT; RADICAL REACTION; REDUCTION KINETICS; CATALYSIS; CHEMISTRY; OXIDATION REDUCTION REACTION;

CATALYSIS; FERROUS COMPOUNDS; FREE RADICALS; INDICATORS AND REAGENTS; IRON; NONHEME IRON PROTEINS; OXIDATION-REDUCTION; OXYGEN; SCANDIUM; TETRAPHENYLBORATE;

EID: 84901936416     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja502732p     Document Type: Article

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