Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron(IV)-oxo complex

Journal of the American Chemical Society

Volumn 133, Issue 14, 2011, Pages 5236-5239

  Park, Jiyun ^a   Morimoto, Yuma ^b   Lee, Yong Min ^a   Nam, Wonwoo ^a   Fukuzumi, Shunichi ^a,b  

^a Ewha Womans University   (South Korea)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON TRANSFER; HEME IRON; METAL ION EFFECT; ONE-ELECTRON OXIDATION; OXO COMPLEXES; OXYGEN TRANSFER; SULFOXIDATION;

ELECTRON TRANSITIONS; METAL IONS; OXYGEN; PORPHYRINS; SCANDIUM;

IRON COMPOUNDS;

ANISOLE DERIVATIVE; METAL COMPLEX; METAL ION; NONHEME IRON PROTEIN; OXYGEN; SCANDIUM; THIOANISOLE; UNCLASSIFIED DRUG;

ARTICLE; ELECTRON; ELECTRON TRANSPORT; OXIDATION; OXYGEN TRANSPORT; SULFOXIDATION;

ELECTRON TRANSPORT; HEME; IRON; ORGANOMETALLIC COMPOUNDS; OXYGEN; SAFROLE; SPECTROPHOTOMETRY, ULTRAVIOLET; SULFIDES;

EID: 79953687693     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja200901n     Document Type: Article

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