Computational ligand design for the reductive elimination of ArCF 3 from a small bite angle PdII complex: Remarkable effect of a perfluoroalkyl phosphine

Angewandte Chemie - International Edition

Volumn 53, Issue 23, 2014, Pages 5903-5906

  Nielsen, Mads C ^b   Bonney, Karl J ^a   Schoenebeck, Franziska ^a,b  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b ETH ZURICH   (Switzerland)

Author keywords

computational chemistry; ligand effects; palladium; reductive elimination; trifluoromethylation

Indexed keywords

COMPUTATIONAL CHEMISTRY; DESIGN; ORGANOMETALLICS; PALLADIUM; PALLADIUM COMPOUNDS; PHOSPHORUS COMPOUNDS;

COMPUTATIONAL DESIGN; COMPUTATIONAL STUDIES; EXPERIMENTAL VERIFICATION; LIGAND EFFECT; PROOF OF PRINCIPLES; QUANTITATIVE FORMATION; REDUCTIVE ELIMINATION; TRIFLUOROMETHYLATION;

LIGANDS;

EID: 84901755402     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201400837     Document Type: Article

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