Trans-difluoro complexes of palladium(II)

Journal of the American Chemical Society

Volumn 131, Issue 3, 2009, Pages 918-919

  Grushin, Vladimir V ^a   Marshall, William J ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

4-TERT-BUTYLPYRIDINE; BOND DISTANCE; C-F BONDS; MECHANISM OF FORMATION; PD BLACK; SQUARE COMPLEX; THERMAL DECOMPOSITIONS;

BENZENE; PALLADIUM; PYROLYSIS;

PALLADIUM COMPOUNDS;

PALLADIUM;

ARTICLE; CHEMICAL BOND; CHEMICAL COMPOSITION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DECOMPOSITION; FLUORINE NUCLEAR MAGNETIC RESONANCE; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; STOICHIOMETRY;

EID: 67749084454     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808975a     Document Type: Article

References (38)

1. For reviews, see: (a) Doherty, N. M.; Hoffmann, N. W. Chem. Rev. 1991, 91, 553.
2. (b) Murphy, E. F.; Murugavel, R.; Roesky, H. W. Chem. Rev. 1997, 97, 3425.
3. (c) Clark, H. C. S.; Holloway, J. H. Adv. Inorg. Fluorides 2000, 51.
4. (d) Grushin, V. V. Chem.-Eur. J. 2002, 8, 1006.
5. Mayer, J. M. Comments Inorg. Chem. 1988, 8, 125.
6. Caulton, K. G. New J. Chem. 1994, 18, 25.
7. (a) Grushin, V. V. Organometallics 2000, 19, 1888.
8. (b) Grushin, V. V.; Marshall, W. J. Angew. Chem., Int. Ed. 2002, 41, 4476.
9. (c) Marshall, W. J.; Grushin, V. V. Organometallics 2003, 22, 555.
10. (d) Grushin, V. V.; Marshall, W. J. J. Am. Chem. Soc. 2006, 128, 12644.
11. (e) Grushin, V. V.; Marshall, W. J. Organometallics 2007, 26, 4997.
12. (f) Grushin, V. V.; Marshall, W. J. Organometallics 2008, 27, 4825.
13. Fraser, S. L.; Antipin, M. Yu.; Khroustalyov, V. N.; Grushin, V. V. J. Am. Chem. Soc. 1997, 119, 4769.
14. Marshall, W. J.; Grushin, V. V. Organometallics 2004, 23, 3343.
15. (a) Kaspi, A. W.; Yahav-Levi, A.; Goldberg, I.; Vigalok, A. Inorg. Chem. 2008, 47, 5.
16. (b) Yahav, A.; Goldberg, I.; Vigalok, A. Inorg. Chem. 2005, 44, 1547.
17. (c) Yahav, A.; Goldberg, I.; Vigalok, A. J. Am. Chem. Soc. 2003, 125, 13634.
18. Flemming, J. P.; Pilon, M. C.; Borbulevitch, O. Ya.; Antipin, M. Yu.; Grushin, V. V. Inorg. Chim. Acta 1998, 280, 87.
19. (a) Marshall, W. J.; Thorn, D. L.; Grushin, V. V. Organometallics 1998, 17, 5427.
20. (b) Jasim, N. A.; Perutz, R. N.; Whitwood, A. C.; Braun, T.; Izundu, J.; Neumann, B.; Rothfeld, S.; Stammler, H.-G. Organometallics 2004, 23, 6140.
21. Gil-Rubio, J.; Weberndorfer, B.; Werner, H. J. Chem. Soc., Dalton Trans. 1999, 1437.
22. Grushin, V. V.; Marshall, W. J. J. Am. Chem. Soc. 2004, 126, 3068.
23. 13
24. See Supporting Information for details.
25. 14b
26. (b) Nova, A.; Erhardt, S.; Jasim, N. A.; Perutz, R. N.; Macgregor, S. A.; McGrady, J. E.; Whitwood, A. C. J. Am. Chem. Soc. 2008, 130, 15499.
27. Leyssens, T.; Peeters, D.; Orpen, A. G.; Harvey, J. N. Organometallics 2007, 26, 2637.
28. Poulton, J. T.; Sigalas, M. P.; Folting, K.; Streib, W. E.; Eisenstein, O.; Caulton, K. G. Inorg. Chem. 1994, 33, 1476.
29. Abu-Hasanayn, F.; Goldman, A. S.; Krogh-Jespersen, K. Inorg. Chem. 1994, 33, 5122.
30. Becker, C.; Kieltsch, I.; Broggini, D.; Mezzetti, A. Inorg. Chem. 2003, 42, 8417. Mezzetti, A.; Becker, C. Helv. Chim. Acta 2002, 85, 2686.
31. Holland, P. L.; Andersen, R. A.; Bergman, R. G. Comments Inorg. Chem. 1999, 21, 115.
32. Klopman, G. In Chemical Reactivity and Reaction Paths; Klopman, G., Ed.; John Wiley and Sons: New York, 1974; p 55.
33. Drago, R. S. Applications of Electrostatic-Covalent Models in Chemistry; Surfside: Gainesville, FL, 1994.
34. Joerg, S.; Webster, C. E.; Drago, R. S.; Sales, J. Polyhedron 1999, 18, 1097.
35. 7,8,14b,23c
36. (b) Landis, C. R.; Firman, T. K.; Root, D. M.; Cleveland, T. J. Am. Chem. Soc. 1998, 120, 1842.
37. 13 pointing to the cis influence of the F and I ligands being almost the same.
38. 18