Metal-alkyl bond protonolysis studies of (dfepe)Pt(Me)X complexes in acidic media

Organometallics

Volumn 19, Issue 4, 2000, Pages 615-621

  Bennett, Byron L ^a   Hoerter, Justin M ^a   Houlis, James F ^a   Roddick, Dean M ^a  

^a UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000026023     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990743x     Document Type: Article

References (48)

1. (a) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science Books: Mill Valley, CA, 1987.
2. (b) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 2nd ed.; Wiley-Interscience: New York, 1994.
3. Bennett, B. L.; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187.
4. Houlis, J. F.; Roddick, D. M. J. Am. Chem. Soc. 1998, 120, 11020.
5. (a) Barone, V.; Bencini, A.; Totti, F.; Uytterhoeven, M. G. Organometallics 1996, 15, 1465.
6. (b) Barbaro, P.; Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, A.; Vacca, A. Inorg. Chem. 1994, 33, 6163.
7. (c) Nugent, W. A.; Kochi, J. K. J. Am. Chem. Soc. 1976, 98, 5979.
8. (d) Jensen, F. R.; Rickborn, B. Electrophilic Substitution of Organomercurials; McGraw-Hill: New York, 1968.
9. Johnson, M. D. Acc. Chem. Res. 1978, 11, 57.
10. (a) Belluco, U.; Michelin, R. A.; Uguagliati, P.; Crociani, B. J. Organomet. Chem. 1983, 250, 565.
11. (b) Uguagliati, P.; Michelin, R. A.; Belluco, U.; Ros, R. J. Organomet. Chem. 1979, 769, 115.
12. (c) Belluco, U.; Giustiniani, M.; Graziani, M. J. Am. Chem. Soc. 1967, 89, 6494.
13. (d) Belluco, U.; Croatto, U.; Uguagliati, P.; Pietropaolo, R. Inorg. Chem. 1967, 6, 718.
14. (a) Kondo, Y.; Ishikawa, M.; Ishihara, K. Inorg. Chim. Acta 1996, 241, 81.
15. (b) Alibrandi, G.; Minniti, D.; Monsù Scolaro, L.; Romeo, R. Inorg. Chem. 1988, 27, 318.
16. (c) Romeo, R.; Minniti, D.; Lanza, S. J. Organomet. Chem. 1979, 165, C36.
17. (d) Romeo, R.; Minniti, D.; Lanza, S.; Uguagliati, P.; Belluco, U. Inorg. Chem. 1978, 17, 2813.
18. (a) Alibrandi, G.; Minniti, D.; Romeo, R.; Uguagliati, P.; Calligaro, L.; Belluco, U. Inorg. Chim. Acta 1986, 112, L15.
19. (b) Alibrandi, G.; Minniti, D.; Romeo, R.; Uguagliati, P.; Calligaro, L.; Belluco, U.; Crociani, B. Inorg. Chim. Acta 1985, 100, 107.
20. (a) Holtcamp, M. W.; Labinger, J. A.; Bercaw, J. E. Inorg. Chim. Acta 1997, 265, 117.
21. (b) Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1996, 118, 5961.
22. (c) Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1995, 117, 9371.
23. (a) Hill, G. S.; Rendina, L. M.; Puddephatt, R. J. Organometallics 1995, 14, 4966.
24. (b) Jawad, J. K.; Puddephatt, R. J.; Stalteri, M. A. Inorg. Chem. 1982, 21, 332.
25. 0 values, see: (a) Olah, G. A.; Surya Prakash, G. K.; Sommer, J. Superacids; Wiley-Interscience: New York, 1985. (b) O'Donnell, T. A. Superacids and Acidic Melts as Inorganic Chemical Reaction Media; VCH: New York, 1993.
26. 0 values, see: (a) Olah, G. A.; Surya Prakash, G. K.; Sommer, J. Superacids; Wiley-Interscience: New York, 1985. (b) O'Donnell, T. A. Superacids and Acidic Melts as Inorganic Chemical Reaction Media; VCH: New York, 1993.
27. Bennett, M. A.; Appleton, T. G. Inorg. Chem. 1978, 17, 738.
28. 4) has been reported: Minkov, A. I.; Efimov, O. A.; Eremenko, N. K., Izv. Akad. Nauk SSSR 1989, 38, 899.
29. No additional solution species were noted. The decomposition of (dfepe)Pt compounds in the presence of water may be due to hydrolysis of the perfluorinated ligand.
30. (a) Puddephatt, R. J.; Johnstone, R. A. W.; Behan, J. J. Chem. Soc., Chem. Commun. 1978, 444.
31. (b) Puddephatt, R. J.; Dignard-Bailey, L.; Bancroft, M.; Yang, D.; Tse, J. S. Inorg. Chem. 1990, 29, 2487.
32. (a) Muller, N. J. Chem. Phys. 1962, 36, 359.
33. (b) Bent, H. A. Chem. Rev. 1961, 61, 275.
34. Drago, R. S. Physical Methods for Chemists, 2nd ed.; Saunders: Orlando, FL; pp 252-254.
35. Parkin, G.; Bercaw, J. E. Polyhedron 1988, 7, 2053.
36. (a) Clark, H. C.; Manzer, L. E.; Ward, J. E. H. Can. J. Chem. 1874, 52, 1165.
37. (b) Chisholm, M. H.; Clark, H. C.; Manzer, L. E.; Stothers, J. B.; Ward, J. E. H. J. Am. Chem. Soc. 1973, 95, 8574.
38. Peters, R. G.; White, S.; Roddick, D. M. Organometallics 1998, 17, 4493.
39. Chisholm, M. H.; Godleski, S. Prog. Inorg. Chem. 1976, 20, 299.
40. Mann, B. E. Adv. Organomet. Chem. 1974, 12, 135.
41. 2 coupling value: (a) Calves, J.-Y.; Gillespie, R. J. J. Chem. Soc., Chem. Commun. 1976, 506. (b) Olah, G. A.; DeMember, J. R.; Schlosberg, R. H. J. Am. Chem. Soc. 1969, 91, 2112.
42. 2 coupling value: (a) Calves, J.-Y.; Gillespie, R. J. J. Chem. Soc., Chem. Commun. 1976, 506. (b) Olah, G. A.; DeMember, J. R.; Schlosberg, R. H. J. Am. Chem. Soc. 1969, 91, 2112.
43. Thorn, D. L. Organometallics 1998, 17, 348.
44. Proton association with halide ligands is well-established: Kuhlman, R. Coord. Chem. Rev. 1997, 167, 205.
45. D(2nd) data was not possible.
46. Melander, L.; Saunders, W. H. Reaction Rates of Isotopic Molecules; Krieger: Malabar, FL, 1987; Chapter 7.
47. Ernst, M. F.; Roddick, D. M. Inorg. Chem. 1989, 28, 1624.
48. Merwin, R. K.; Schnabel, R. C.; Koola, J. D.; Roddick, D. M. Organometallics 1992, 11, 2972.