Synthesis and reactions of dihydridobis[1,2-bis(bis(trifluoromethyl)phosphino)ethane]ruthenium(II), RuH2(dfmpe)2

Organometallics

Volumn 16, Issue 9, 1997, Pages 1841-1845

  Field, Leslie D ^a   Wilkinson, Matthew P ^a  

^a UNIVERSITY OF SYDNEY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0343730296     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960311b     Document Type: Article

References (41)

1. For early references, see, for example: (a) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1978, 100, 4080-4089. (b) English, A. D.; Ittel, S. D.; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 7577-7585. (c) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 1742-1751. (d) Ittel, S. D.; Tolman, C. A.; Krusic, P. J.; English, A. D.; Jesson, J. P. Inorg. Chem. 1978, 17, 3432-3438.
2. For early references, see, for example: (a) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1978, 100, 4080-4089. (b) English, A. D.; Ittel, S. D.; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 7577-7585. (c) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 1742-1751. (d) Ittel, S. D.; Tolman, C. A.; Krusic, P. J.; English, A. D.; Jesson, J. P. Inorg. Chem. 1978, 17, 3432-3438.
3. For early references, see, for example: (a) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1978, 100, 4080-4089. (b) English, A. D.; Ittel, S. D.; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 7577-7585. (c) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 1742-1751. (d) Ittel, S. D.; Tolman, C. A.; Krusic, P. J.; English, A. D.; Jesson, J. P. Inorg. Chem. 1978, 17, 3432-3438.
4. For early references, see, for example: (a) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1978, 100, 4080-4089. (b) English, A. D.; Ittel, S. D.; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 7577-7585. (c) English, A. D.; Ittel, S. D; Jesson, J. P.; Tolman, C. A. J. Am. Chem. Soc. 1979, 101, 1742-1751. (d) Ittel, S. D.; Tolman, C. A.; Krusic, P. J.; English, A. D.; Jesson, J. P. Inorg. Chem. 1978, 17, 3432-3438.
5. Baker, M. V.; Field, L. D. Organometallics 1986, 5, 821.
6. Baker, M. V.; Field, L. D. J. Am. Chem. Soc. 1987, 109, 2825-2826.
7. Baker, M. V.; Field, L. D. J. Am. Chem. Soc. 1986, 108, 7433-7434.
8. Jones, W. D.; Kosar, W. P. J. Am. Chem. Soc. 1986, 108, 393-395.
9. Yau, B. C. Y.; Field, L. D. Unpublished results, B.Sc. Honours Thesis, The University of Sydney, 1988.
10. Cook, R. L.; Morse, J. G. Inorg. Chem. 1982, 21, 4103.
11. See, for example: Schnabel, R. C.; Roddick, D. M. ACS Symp. Ser. 1994, 55, 421-437 and references therein.
12. Ernst, M. F.; Roddick, D. M. Inorg. Chem. 1989, 28, 1624-1627.
13. dfmpe was first made by L. R. Grant (Ph.D. Dissertation, University of Southern California Libraries, 1960, cited by A. B. Burg: Burg, A. B. Acc. Chem. Res. 1969, 2, 353).
14. dfmpe was first made by L. R. Grant (Ph.D. Dissertation, University of Southern California Libraries, 1960, cited by A. B. Burg: Burg, A. B. Acc. Chem. Res. 1969, 2, 353).
15. See, for example: (a) Schnabel, R. C; Carroll, P. S.; Roddick, D. M. Organometallics 1996, 75, 655-62. (b) Schnabel, R. C; Roddick, D. M. Inorg. Chem. 1993, 32, 1513-8. (c) Bennett, B. L; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187-195. (d) Schnabel, R. C; Roddick, D. M. Organometallics 1993, 12, 704-711. (e) Keady, M. S.; Koola, J. D.; Ontko, A. C.; Merwin, R. K.; Roddick, D. M. Organometallics 1992, 11, 3417-3421. (f) Koola, J. D.; Roddick, D. M. J. Am. Chem. Soc. 1991, 113, 1450-1451.
16. See, for example: (a) Schnabel, R. C; Carroll, P. S.; Roddick, D. M. Organometallics 1996, 75, 655-62. (b) Schnabel, R. C; Roddick, D. M. Inorg. Chem. 1993, 32, 1513-8. (c) Bennett, B. L; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187-195. (d) Schnabel, R. C; Roddick, D. M. Organometallics 1993, 12, 704-711. (e) Keady, M. S.; Koola, J. D.; Ontko, A. C.; Merwin, R. K.; Roddick, D. M. Organometallics 1992, 11, 3417-3421. (f) Koola, J. D.; Roddick, D. M. J. Am. Chem. Soc. 1991, 113, 1450-1451.
17. See, for example: (a) Schnabel, R. C; Carroll, P. S.; Roddick, D. M. Organometallics 1996, 75, 655-62. (b) Schnabel, R. C; Roddick, D. M. Inorg. Chem. 1993, 32, 1513-8. (c) Bennett, B. L; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187-195. (d) Schnabel, R. C; Roddick, D. M. Organometallics 1993, 12, 704-711. (e) Keady, M. S.; Koola, J. D.; Ontko, A. C.; Merwin, R. K.; Roddick, D. M. Organometallics 1992, 11, 3417-3421. (f) Koola, J. D.; Roddick, D. M. J. Am. Chem. Soc. 1991, 113, 1450-1451.
18. See, for example: (a) Schnabel, R. C; Carroll, P. S.; Roddick, D. M. Organometallics 1996, 75, 655-62. (b) Schnabel, R. C; Roddick, D. M. Inorg. Chem. 1993, 32, 1513-8. (c) Bennett, B. L; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187-195. (d) Schnabel, R. C; Roddick, D. M. Organometallics 1993, 12, 704-711. (e) Keady, M. S.; Koola, J. D.; Ontko, A. C.; Merwin, R. K.; Roddick, D. M. Organometallics 1992, 11, 3417-3421. (f) Koola, J. D.; Roddick, D. M. J. Am. Chem. Soc. 1991, 113, 1450-1451.
19. See, for example: (a) Schnabel, R. C; Carroll, P. S.; Roddick, D. M. Organometallics 1996, 75, 655-62. (b) Schnabel, R. C; Roddick, D. M. Inorg. Chem. 1993, 32, 1513-8. (c) Bennett, B. L; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187-195. (d) Schnabel, R. C; Roddick, D. M. Organometallics 1993, 12, 704-711. (e) Keady, M. S.; Koola, J. D.; Ontko, A. C.; Merwin, R. K.; Roddick, D. M. Organometallics 1992, 11, 3417-3421. (f) Koola, J. D.; Roddick, D. M. J. Am. Chem. Soc. 1991, 113, 1450-1451.
20. See, for example: (a) Schnabel, R. C; Carroll, P. S.; Roddick, D. M. Organometallics 1996, 75, 655-62. (b) Schnabel, R. C; Roddick, D. M. Inorg. Chem. 1993, 32, 1513-8. (c) Bennett, B. L; Birnbaum, J.; Roddick, D. M. Polyhedron 1995, 14, 187-195. (d) Schnabel, R. C; Roddick, D. M. Organometallics 1993, 12, 704-711. (e) Keady, M. S.; Koola, J. D.; Ontko, A. C.; Merwin, R. K.; Roddick, D. M. Organometallics 1992, 11, 3417-3421. (f) Koola, J. D.; Roddick, D. M. J. Am. Chem. Soc. 1991, 113, 1450-1451.
21. Ernst, M. F.; Roddick, D. M. Organometallics 1990, 9, 1586-1594.
22. Ernst, M. F.; Roddick, D. M. Inorg. Chem. 1990, 29, 3627-3630.
23. Brookhart, M.; Chandler, W. A.; Pfister, A. C.; Santini, C. C.; White, P. S. Organometallics 1992, 11, 1263-1274.
24. Merwin, R. K.; Schnabel, R. C.; Koola, J. D.; Roddick, D. M. Organometallics 1992, 11, 2972-2978.
25. (a) Cronin, L.; Nicasio, M. C.; Perutz, R. N.; Peters, R. G.; Roddick, D. M.; Whittlesey, M. K. J. Am. Chem. Soc. 1995, 117, 10047-10054.
26. (b) Hall, C.; Jones, W. D.; Mawby, R. J.; Osman, R.; Perutz, R. N.; Whittlesey, M. K J. Am. Chem. Soc. 1992, 114, 7425.
27. (c) Whittlesey, M. K.; Mawby, R. J.; Osman, R.; Perutz, R. N.; Field, L. D.; Wilkinson, M. P.; George, M. W. J. Am. Chem. Soc. 1993, 115, 8627.
28. Burg, A. B.; Street, G. B. J. Am. Chem. Soc. 1963, 85, 3522.
29. Burg, A. B.; Street, G. B. Inorg. Chem. 1966, 5, 1532-1537.
30. Phillips, I. G.; Ball, R. G.; Cavell, R. G. Inorg. Chem. 1988, 27, 4038-4045.
31. Field, L. D.; Wilkinson, M. P. Tetrahedron Lett. 1992, 33, 7601-7604.
32. See, for example: Bennett, M. A.; Neumann, H.; Thomas, M.; Wang, X. Q.; Pertici, P.; Salvadori, P.; Vitulli, G. Organometallics 1991, 10, 3237-3245.
33. Jiminez-Tenerio, M.; Carmen Puerta, M.; Valerga, P. Inorg. Chem. 1994, 33, 3515-3520.
34. -3, Z = 2, F(000) = 836.
35. Brookhart, M.; Chandler, W.; Liu, Y.; Pienta, N. J.; Santini, C. C.; Hall, C.; Perutz, R. N.; Timney, J. A. J. Am. Chem. Soc. 1992, 114, 3802.
36. Field, L. D.; Hambley, T. W.; Yau, B. C. K. Inorg. Chem. 1994, 33, 2009-2017.
37. Pertici, P.; Vitulli, G. Inorg. Synth. 1983, 22, 178.
38. Hallman, P. S.; McGarvey, B. R.; Wilkinson, G. J. Chem. Soc. A 1968, 3143.
39. Stuebe, C.; Lankelma, H. P. J. Am. Chem. Soc. 1956, 78, 976.
40. Significant decomposition of dfmpe is observed if the reaction mixture is allowed to warm to room temperature in the presence of excess hepa. The reaction of hepa with elemental sulfur to form hexaethylphosphorus triamide sulfide is rapid (even at low temperature), and warming the reaction mixture to room temperature after the hepa has been sulfurized results in no decomposition of dfmpe.
41. The yield of dfmpe can be increased (to ca. 30%) if the reaction mixture is extracted with perfluorohexanes (3 × 50 mL). No separation of dfmpe from perfluorohexane was attempted.