Direct synthesis of high-valent aryl-Cu(II) and aryl-Cu(III) compounds: Mechanistic insight into arene C-H bond metalation

Journal of the American Chemical Society

Volumn 136, Issue 17, 2014, Pages 6326-6332

  Zhang, Hu ^a,b   Yao, Bo ^a,b   Zhao, Liang ^a   Wang, De Xian ^b   Xu, Bo Qing ^a   Wang, Mei Xiang ^a  

^a Tsinghua University   (China)

^b INSTITUTE OF CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COPPER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS;

AMBIENT CONDITIONS; ATMOSPHERIC CONDITIONS; CATALYZED REACTIONS; CH-BOND ACTIVATION; EXPERIMENTAL EVIDENCE; OXIDATION REACTIONS; REACTION MECHANISM; THEORETICAL CALCULATIONS;

COPPER COMPOUNDS;

CALIXARENE; COPPER DERIVATIVE; ELECTROPHILE; PHENYL GROUP; POLYCYCLIC AROMATIC HYDROCARBON; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; PYRIDINE DERIVATIVE; AROMATIC HYDROCARBON; COPPER; PERCHLORATE;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; HYDROGEN BOND; METALATION; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM YIELD; REACTION ANALYSIS; SYNTHESIS; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; OXIDATION REDUCTION REACTION; X RAY CRYSTALLOGRAPHY;

CATALYSIS; COPPER; CRYSTALLOGRAPHY, X-RAY; HYDROCARBONS, AROMATIC; KINETICS; MODELS, MOLECULAR; OXIDATION-REDUCTION; PERCHLORATES; PYRIDINES;

EID: 84899755638     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja412615h     Document Type: Article

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