N-confused porphyrin-bearing meso-perfluorophenyl groups: A potential agent that forms stable square-planar complexes with Cu(II) and Ag(III)

Organic Letters

Volumn 5, Issue 8, 2003, Pages 1293-1296

  Maeda, Hiromitsu ^a   Osuka, Atsuhiro ^a   Ishikawa, Yuichi ^b   Aritome, Isao ^c   Hisaeda, Yoshio ^c   Furuta, Hiroyuki ^a,c  

^a KYOTO UNIVERSITY   (Japan)

^b OITA UNIVERSITY   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; METHANE; PALLADIUM COMPLEX; PERFLUORO COMPOUND; PHENYL GROUP; PORPHYRIN; SILVER DERIVATIVE;

ARTICLE; CRYSTAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

EID: 0141517642     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol034227l     Document Type: Article

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46. 3, Z = 9, R = 0.0489, wR = 0.1207, GOF = 1.046 (I > 2.0σ(I)).
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52. 22 quantitatively.
53. Introduction of electron-withdrawing groups directly at the NCP core may also be helpful to stabilize the metal complexes. In fact, an airstable Cu(II) complex was also obtained from CN-substituted NCTPP at the confused pyrrole ring. Ishikawa, Y.; Dejima, H.; Furuta, H. Manuscript in preparation.