Facile C-H bond cleavage via a proton-coupled electron transfer involving a C-H⋯CuIIinteraction

Journal of the American Chemical Society

Volumn 132, Issue 35, 2010, Pages 12299-12306

  Ribas, Xavi ^a   Calle, Carlos ^b   Poater, Albert ^a   Casitas, Alicia ^a   Goěmez, Laura ^a   Xifra, Raül ^a   Parella, Teodor ^c   Benet Buchholz, Jordi ^d   Schweiger, Arthur ^b   Mitrikas, George ^b   Solà, Miquel ^a,e   Llobet, Antoni ^d   Stack, T Daniel P ^f  

^a UNIVERSITY OF GIRONA   (Spain)

^b ETH ZURICH   (Switzerland)

^c Universitat Autoànoma de Barcelona   (Spain)

^d INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^e Institut de Qui mica Computacional   (Spain)

^f STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL ACTIVATION; COPPER; DENSITY FUNCTIONAL THEORY; ELECTRON SPECTROSCOPY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSITIONS; ELECTRONS; MAGNETIC RESONANCE; PARAMAGNETIC RESONANCE;

2 ,2 ,6 ,6-TETRAMETHYLPIPERIDINE-1-OXYL; C-H BOND CLEAVAGE; COPPER OXIDATION; DISPROPORTIONATION REACTIONS; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; EQUIMOLAR AMOUNT; LOW TEMPERATURES; PROTON COUPLED ELECTRON TRANSFERS;

CHEMICAL BONDS;

AROMATIC COMPOUND; CARBON; COPPER; HYDROGEN; NICKEL; TEMPOL;

ARTICLE; CHEMICAL BOND; CHEMICAL INTERACTION; DENSITY FUNCTIONAL THEORY; ELECTRON; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; KINETICS; LOW TEMPERATURE; OXIDATION; QUANTITATIVE ANALYSIS;

EID: 77956257479     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja101599e     Document Type: Article

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