Spiroketal-based diphosphine ligands in Pd-catalyzed asymmetric allylic amination of Morita-Baylis-Hillman adducts: Exceptionally high efficiency and new mechanism

Journal of the American Chemical Society

Volumn 136, Issue 1, 2014, Pages 405-411

  Wang, Xiaoming ^a   Guo, Peihua ^a   Han, Zhaobin ^a   Wang, Xubin ^a   Wang, Zheng ^a   Ding, Kuiling ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC SUBSTITUTION; DIPHOSPHINE LIGAND; MECHANISTIC STUDIES; MORITA-BAYLIS-HILLMAN ADDUCTS; ORGANOMETALLIC CATALYSIS; PALLADIUM COMPLEXES; SOLID-STATE STRUCTURES; TERMINAL CARBON ATOMS;

AMINES; ATOMS; LIGANDS; ORGANOMETALLICS; PALLADIUM COMPOUNDS; SUBSTITUTION REACTIONS;

CATALYSIS;

LEWIS BASE; LIGAND; PALLADIUM COMPLEX; SPIROKETAL BASED DIPHOSPHINE LIGAND; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; ENANTIOSELECTIVITY; MORITA BAYLIS HILLMAN ADDUCT; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE;

EID: 84892151261     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja410707q     Document Type: Article

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