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Volumn , Issue , 2008, Pages 357-382

Heterogeneous Enantioselective Hydrogenation on Metal Surface Modified by Chiral Molecules

Author keywords

Chiral modifier; Enantioselectivity; Heterogeneous catalysis; Hydrogenation; Molecular recognition; Surface modification

Indexed keywords


EID: 84890982571     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527623013.ch10     Document Type: Chapter
Times cited : (12)

References (153)
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    • After the submission of the draft on June, 2007, many progress has been made in this field. Many of them will be reviewed somewhere else, but here, one good review is added.
    • After the submission of the draft on June, 2007, many progress has been made in this field. Many of them will be reviewed somewhere else, but here, one good review is added. Mallat, T., Orglmeister, E., Baiker, A. (2007) Chemical Review, 107, 4863-4890.
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  • 2
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    • For results before 2000, see:, (eds), Wiley-VCH Verlag GmbH, Weinheim.
    • For results before 2000, see: De Vos, D.E., Vankelecom, I.F.J. and Jacobs, P.A. (eds) (2000) Chiral Catalyst Immobilization and Recycling, Wiley-VCH Verlag GmbH, Weinheim.
    • (2000)
    • De Vos, D.E.1    Vankelecom, I.F.J.2    Jacobs, P.A.3
  • 3
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    • See also:, For other reviews, see references cited in each section.
    • See also: Blaser, H.-U. (1991) Tetrahedron: Asymmetry, 2, 843-66. For other reviews, see references cited in each section.
    • (1991) Tetrahedron: Asymmetry , vol.2 , pp. 843-866
    • Blaser, H.-U.1
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    • Tailored Metal Catalyst
    • (ed. Y. Iwasawa), Reidel, Dordrecht
    • Tai, A. and Harada, T. (1986)Tailored Metal Catalyst (ed. Y. Iwasawa), Reidel, Dordrecht, pp. 265-324.
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  • 108
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    • For heterogeneous enantioselective catalysts there are some more candidates on the borderline of the definition. For example, when a certain α,β-unsaturated ketone was hydrogenated over Pd/C in the presence of 0.5 equiv. ephedrine, up to 36% ee of the product was obtained. It is not clear whether the demanded amount of the chiral molecule indicates a necessity of the interaction with the substrate in solution, or just a weak adsorption constant of the chiral molecule.
    • For heterogeneous enantioselective catalysts there are some more candidates on the borderline of the definition. For example, when a certain α,β-unsaturated ketone was hydrogenated over Pd/C in the presence of 0.5 equiv. ephedrine, up to 36% ee of the product was obtained. It is not clear whether the demanded amount of the chiral molecule indicates a necessity of the interaction with the substrate in solution, or just a weak adsorption constant of the chiral molecule. Thorey, C., Hénin, F. and Muzart, J. (1996) Tetrahedron: Asymmetry, 7, 975-6.
    • (1996) Tetrahedron: Asymmetry , vol.7 , pp. 975-976
    • Thorey, C.1    Hénin, F.2    Muzart, J.3
  • 109
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    • Comptes Rendus de l'Academie des Sciences. Paris
    • Perez, J.R.G., Malthête, J. and Jacques, J. (1985)Comptes Rendus de l'Academie des Sciences. Paris, 300 (II), 169-72.
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    • The 99th Meeting of the Catalysis Society of Japan
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    • Sugimura, T., Uchida, T., Yokota, M. and Watanabe, J. (2007)The 99th Meeting of the Catalysis Society of Japan, Osaka, March 2007, Abstract, No. 2.
    • (2007)
    • Sugimura, T.1    Uchida, T.2    Yokota, M.3    Watanabe, J.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.