Role of acetic acid added to the reaction media for the enantio-differentiating hydrogenation of methyl acetoacetate over a tartaric acid-modified nickel catalyst

Catalysis Letters

Volumn 105, Issue 1-2, 2005, Pages 41-45

  Osawa, Tsutomu ^a   Ando, Masashi ^a   Sakai, Saori ^a   Harada, Tadao ^b   Takayasu, Osamu ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

^b RYUKOKU UNIVERSITY   (Japan)

Author keywords

Acetic acid; Enantio differentiating; Hydrogenation rate; Repeated uses; Site specific acceleration; Tartaric acid modified nickel

Indexed keywords

CARBOXYLIC ACIDS; CATALYSTS; HYDROGENATION; NICKEL; REACTION KINETICS;

ENANTIO-DIFFERENTIATING; HYDROGENATION RATE; REPEATED SPECIES; SITE SPECIES ACCELERATION; TARTARIC ACID-MODIFIED NICKEL;

ACETIC ACID;

EID: 27144482477     PISSN: 1011372X     EISSN: 1572879X     Source Type: Journal    
DOI: 10.1007/s10562-005-8003-3     Document Type: Article

References (19)

1. H.U. Blaser and E. Schmidt, Asymmetric Catalysis on Industrial Scale: Challenges, Approaches and Solutions (Chemistry) (John Wiley & Sons, New York, 2004).
2. I.F.J. Vankelecom and P.A. Jacobs in: Chiral Catalyst Immobilization and Recycling, eds. D.E. De Vos, I.F.J. Vankelecom and P.A. Jacobs (Wiley-VCH 2000, 19) and references therein.
3. H.U. Blaser, C. Malan, B. Pugin, F. Spindler, H. Steiner and M. Studer, Adv. Syn. Catal. 345 (2003) 103 and references therein.
4. J.M. Thomas and R. Raja, J. Organomet. Chem. 689 (2004) 4110 and references therein.
5. A. Tai and T. Harada, in: Tailored Metal Catalysts, ed. Y. Iwasawa, (Reidel, Dordrecht, 1986) p. 265 and references therein.
6. A. Tai and T. Sugimura, in:Chiral Catalyst Immobilization and Recycling, eds. D.E. De Vos, I.F.J. Vankelecom and P.A. Jacobs (Wiley-VCH, 2000) p. 173 and references therein.
7. T. Osawa, T. Harada and O. Takayasu, Top. Catal. 13 (2000) 155 and references therein.
8. T. Harada, M. Yamamoto, S. Onaka, M. Imaida, H. Ozaki, A. Tai and Y. Izumi, Bull. Chem. Soc. Jpn. 54 (1981) 2323.
9. T. Osawa, S. Sakai, K. Deguchi, T. Harada and O. Takayasu, J. Mol. Catal. A: Chem. 185 (2002) 65.
10. H. Ozaki, A. Tai, S. Kobatake, H. Watanabe and Y. Izumi, Bull. Chem. Soc. Jpn. 51 (1978) 3559.
11. I. Yasumori, M. Yokozeki and Y. Inoue, Faraday Discuss. Chem. Soc. 72 (1982) 385.
12. Y. Nitta, T. Imanaka and S. Teranishi, J. Catal. 80 (1983) 31.
13. W.M.H. Sachtler, Chem. Ind. (Dekker) 22 (1985) 189.
14. M.A. Keane, J. Chem. Soc., Faraday Trans. 93 (1997) 201.
15. T. Sugimura, S. Nakagawa and A. Tai, Bull. Chem. Soc. Jpn. 75 (2002) 355.
16. Y. Orito, S. Niwa and S. Imai, Yukigoseikagaku 35 (1977) 672.
17. T. Harada, T. Kawamura, S. Haikawa and T. Osawa, J. Mol. Catal. 93 Z(1994) 211.
18. T. Osawa, M. Ando, T. Harada and O. Takayasu, Bull. Chem. Soc. Jpn in press.
19. T. Osawa, K. Sawada, T. Harada and O. Takayasu, Appl. Catal. A: Gen. 264 (2004) 33.