Specific acceleration of the hydrogenation of methyl acetoacetate on enantio-differentiating sites of a tartaric acid-modified nickel catalyst by the addition of acetic acid to the reaction media

Bulletin of the Chemical Society of Japan

Volumn 78, Issue 7, 2005, Pages 1371-1372

  Osawa, Tsutomu ^a   Ando, Masashi ^a   Harada, Tadao ^b   Takayasu, Osamu ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

^b RYUKOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ADDITION REACTIONS; CATALYSTS; ORGANIC ACIDS;

ACID-MODIFIED NICKEL CATALYSTS; ENANTIO-DIFFERENTIATING SITES; REACTION MEDIA;

HYDROGENATION;

ACETIC ACID; ACETOACETIC ACID; ACETOACETIC ACID METHYL ESTER; NICKEL; TARTARIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; ENANTIOSELECTIVITY; HYDROGENATION; ORGANIC CHEMISTRY; REACTION ANALYSIS; SYNTHESIS;

EID: 23244433353     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.78.1371     Document Type: Article

References (8)

1. H. U. Blaser and E. Schmidt, "Asymmetric Catalysis on Industrial Scale: Challenges, Approaches, and Solutions (Chemistry)," John Wiley & Sons, New York (2004).
2. A. Tai and T. Harada, "Tailored Metal Catalysts," ed by Y. Iwasawa, Reidel, Dordrecht (1986), p. 265, and references therein.
3. A. Tai and T. Sugimura, "Chiral Catalyst Immobilization and Recycling," ed by D. E. De Vos, I. F. J. Vankelecom, and P. A. Jacobs, Wiley-VCH (2000), p. 173, and references therein.
4. T. Osawa, T. Harada, and O. Takayasu, Top. Catal., 13, 155 (2000), and references therein.
5. T. Harada, M. Yamamoto, S. Onaka, M. Imaida, H. Ozaki, A. Tai, and Y. Izumi, Bull. Chem. Soc. Jpn., 54, 2323 (1981).
6. T. Osawa, S. Sakai, K. Deguchi, T. Harada, and O. Takayasu, J. Mol. Catal. A: Chem., 185, 65 (2002).
7. Y. Orito, S. Niwa, and S. Imai, Yuki Gosei Kagaku Kyokaishi, 35, 672 (1977).
8. T. Harada, T. Kawamura, S. Haikawa, and T. Osawa, J. Mol. Catal., 93, 211 (1994).