Transition-metal-catalyzed allylic substitution reactions: Stereoselective construction of α- And β-substituted carbonyl compounds

Synthesis (Germany)

Volumn 45, Issue 23, 2013, Pages 3179-3198

  Oliver, Samuel ^a   Evans, P Andrew ^b  

^a UNIVERSITY OF LIVERPOOL   (United Kingdom)

^b QUEEN S UNIVERSITY   (Canada)

Author keywords

acyl anion; allylic substitution; asymmetric catalysis; enamine; enolate; metal catalyzed; silyl enol ethers

Indexed keywords

ACYL ANIONS; ALLYLIC SUBSTITUTION; ASYMMETRIC CATALYSIS; ENAMINES; ENOLATES; METAL-CATALYZED; SILYL ENOL ETHERS;

ALLYLATION; CARBONYL COMPOUNDS; CATALYSIS; CHEMICAL COMPOUNDS; COPPER; ETHERS; NEGATIVE IONS; NUCLEOPHILES; STEREOCHEMISTRY; STEREOSELECTIVITY; SUBSTITUTION REACTIONS;

OLEFINS;

ACETOPHENONE ENOLATE; ACYCLIC ENOLATE DERIVATIVE; ACYL COMPOUND; ALLYL COMPOUND; ALPHA CARBONYL DERIVATIVE; BETA CARBONYL DERIVATIVE; BORON ENOLATE DERIVATIVE; CARBONYL DERIVATIVE; CHEMICAL COMPOUND; CHROMIUM; COPPER ENOLATE DERIVATIVE; CYANOHYDRIN DERIVATIVE; CYCLOPROPANE; ENAMINE DERIVATIVE; ENOL CARBONATE DERIVATIVE; ENOLSTANNANE DERIVATIVE; ETHER DERIVATIVE; IMINE; LITHIUM ENOLATE DERIVATIVE; MAGNESIUM ENOLATE DERIVATIVE; METAL; METAL ENOLATE DERIVATIVE; NUCLEOPHILE; PSEUDOEPHEDRINE; SILYLENOL ETHER DERIVATIVE; SODIUM ENOLATE DERIVATIVE; TIN ENOLATE DERIVATIVE; TRIBUTYLTIN ENOLATE DERIVATIVE; UNCLASSIFIED DRUG; ZINC ENOLATE DERIVATIVE;

ALKYLATION; ALLYLATION; ARYLATION; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL STRUCTURE; CHIRALITY; DECARBOXYLATION; DENSITY FUNCTIONAL THEORY; DERIVATIZATION; ENANTIOMER; ENANTIOSELECTIVITY; EPOXIDATION; HYDROLYSIS; ISOMERIZATION; PROTON TRANSPORT; PURIFICATION; RACEMIZATION; REVIEW; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION;

EID: 84888128548     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0033-1338538     Document Type: Review

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