Dissection of activation parameters in the bell-shaped α-effect following solvent modulation (DMSO-H2O Media)

Journal of Organic Chemistry

Volumn 78, Issue 17, 2013, Pages 8689-8695

  Um, Ik Hwan ^a   Kang, Ji Sun ^a   Kim, Min Young ^a   Buncel, Erwin ^b  

^a Ewha Womans University   (South Korea)

^b QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

DISSECTION; ENTHALPY; ENTROPY; NUCLEOPHILES; SOLVENTS;

ACTIVATION PARAMETER; ALPHA-EFFECT; ENTROPY OF ACTIVATION; SOLVENT COMPOSITION; SOLVENT DEPENDENCE; TRANSITION STATE;

CHEMICAL ACTIVATION;

4 CHLOROPHENOL; 4 NITROPHENOXIDE; 4 NITROPHENYL THIONOBENZOATE; BUTANE 2,3 DIONE MONOXIMATE; CHEMICAL COMPOUND; DIMETHYL SULFOXIDE; NUCLEOPHILE; SOLVENT; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENTHALPY; ENTROPY; NUCLEOPHILICITY; TEMPERATURE;

EID: 84883821204     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo401415f     Document Type: Article

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