Kinetic studies on nucleophilic substitution reactions of O-Aryl thionobenzoates with azide, cyanide, and hydroxide: Contrasting reactivity and mechanism

Journal of Organic Chemistry

Volumn 74, Issue 3, 2009, Pages 1212-1217

  Um, Ik Hwan ^a   Kim, Eun Hee ^a   Lee, Ji Youn ^a  

^a Ewha Womans University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

AZIDE IONS; CARBONYL FUNCTIONALITIES; ELECTRON-DONATING SUBSTITUENTS; HAMMETT CORRELATIONS; HAMMETT PLOTS; KINETIC STUDIES; LEAVING GROUPS; NUCLEOPHILIC SUBSTITUTION REACTIONS; POLARIZABILITY; RATE-DETERMINING STEPS; RESONANCE INTERACTIONS;

ALKALINITY; CYANIDES; DIMETHYL SULFOXIDE; ESTERIFICATION; ESTERS; KINETIC THEORY; MEATS; SUBSTITUTION REACTIONS;

RESPIRATORY MECHANICS;

AZIDE; BENZOIC ACID DERIVATIVE; CYANIDE; HYDROXIDE; NUCLEOPHILE; O ARYLTHIONOBENZOATE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; KINETICS; MOLECULAR INTERACTION; POLARIZATION; SUBSTITUTION REACTION;

AZIDES; BENZOATES; CYANIDES; HYDROXIDES; KINETICS; STRUCTURE-ACTIVITY RELATIONSHIP; SULFUR COMPOUNDS;

EID: 64549162023     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo802446y     Document Type: Article

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