Direct β-activation of saturated aldehydes to formal michael acceptors through oxidative NHC catalysis

Angewandte Chemie - International Edition

Volumn 52, Issue 33, 2013, Pages 8588-8591

  Mo, Junming ^a   Shen, Liang ^a   Chi, Yonggui Robin ^a  

^a Nanyang Technological University   (Singapore)

Author keywords

activation; Michael addition; N heterocyclic carbene; organocatalysis; synthetic methods

Indexed keywords

1 ,3-DIKETONES; CARBON FUNCTIONALIZATION; ENANTIOSELECTIVE; MICHAEL ACCEPTORS; MICHAEL ADDITIONS; N-HETEROCYCLIC CARBENES; ORGANOCATALYSIS; SYNTHETIC METHODS;

ADDITION REACTIONS; ALDEHYDES; ENANTIOSELECTIVITY; ESTERIFICATION; ESTERS; KETONES; REACTION KINETICS;

CATALYSIS;

ALDEHYDE; CARBENE; DRUG DERIVATIVE; ESTER; HETEROCYCLIC COMPOUND; KETONE; METHANE; TRIAZOLE DERIVATIVE;

Β-ACTIVATION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; MICHAEL ADDITION; N-HETEROCYCLIC CARBENE; ORGANOCATALYSIS; OXIDATION REDUCTION REACTION; STEREOISOMERISM; SYNTHETIC METHODS;

Β-ACTIVATION; MICHAEL ADDITION; N-HETEROCYCLIC CARBENE; ORGANOCATALYSIS; SYNTHETIC METHODS;

ALDEHYDES; CATALYSIS; ESTERS; HETEROCYCLIC COMPOUNDS; KETONES; METHANE; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; STEREOISOMERISM; TRIAZOLES;

EID: 84882366287     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201302152     Document Type: Article

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