Oxidative γ-addition of enals to trifluoromethyl ketones: Enantioselectivity control via lewis acid/n-heterocyclic carbene cooperative catalysis

Journal of the American Chemical Society

Volumn 134, Issue 21, 2012, Pages 8810-8813

  Mo, Junming ^a   Chen, Xingkuan ^a   Chi, Yonggui Robin ^a  

^a Nanyang Technological University   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENES; COOPERATIVE CATALYSIS; FUNCTIONALIZATIONS; LEWIS ACID; N-HETEROCYCLIC CARBENES; TRIFLUOROMETHYLKETONE;

CATALYSIS; ENANTIOSELECTIVITY; KETONES;

ORGANIC COMPOUNDS;

CARBENE; CARBON; KETONE; LEWIS ACID;

ADDITION REACTION; ARTICLE; BIOTRANSFORMATION; CATALYSIS; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; ENANTIOSELECTIVITY; NUCLEOPHILICITY; OXIDATION; OXIDATION REDUCTION REACTION; REACTION TIME; STRUCTURE ANALYSIS;

ALKENES; CATALYSIS; HETEROCYCLIC COMPOUNDS; KETONES; LEWIS ACIDS; METHANE; OXIDATION-REDUCTION; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 84861633806     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja303618z     Document Type: Article

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