Mechanistic dichotomy in the asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by chiral pyridine N-oxides

Chemistry - A European Journal

Volumn 19, Issue 28, 2013, Pages 9167-9185

  Malkov, Andrei V ^a,b   Stončius, Sigitas ^a,c   Bell, Mark ^a,d   Castelluzzo, Fabiomassimo ^a,e   Ramírez López, Pedro ^a,f   Biedermannová, Lada ^a,g   Langer, Vratislav ^h   Rulíšek, Lubomír ⁱ   Kočovský, Pavel ^a,j  

^a Technology and Innovation Centre   (United Kingdom)

^b LOUGHBOROUGH UNIVERSITY   (United Kingdom)

^c VILNIUS UNIVERSITY   (Lithuania)

^d UNIVERSITY OF DUNDEE   (United Kingdom)

^e Bayer SpA Italy   (Italy)

^f UNIVERSITY OF SEVILLE   (Spain)

^g INSTITUTE OF BIOTECHNOLOGY   (Czech Republic)

^h CHALMERS UNIVERSITY OF TECHNOLOGY   (Sweden)

ⁱ INSTITUTE OF ORGANIC CHEMISTRY AND BIOCHEMISTRY   (Czech Republic)

^j STOCKHOLM UNIVERSITY   (Sweden)

more..

Author keywords

allylation; allylsilanes; calculations; organocatalysis; pyridine N oxides

Indexed keywords

ALLYLSILANES; ASYMMETRIC ALLYLATION; COMPUTATIONAL DATA; COMPUTATIONAL INVESTIGATION; DIASTEREOSELECTIVE; ORGANOCATALYSIS; PYRIDINE N-OXIDES; STERICALLY DEMANDING;

ALDEHYDES; ALLYLATION; CALCULATIONS; CATALYSIS; PYRIDINE; REACTION KINETICS; STEREOCHEMISTRY;

CATALYST SELECTIVITY;

EID: 84879881526     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201203817     Document Type: Article

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