Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes

Tetrahedron Letters

Volumn 46, Issue 1, 2005, Pages 157-159

  Nakajima, Makoto ^a   Kotani, Shunsuke ^a,b   Ishizuka, Tadao ^a   Hashimoto, Shunichi ^b  

^a KUMAMOTO UNIVERSITY   (Japan)

^b HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Allylation; Catalyst; Enantioselectivity; Phosphine oxide

Indexed keywords

ALDEHYDE DERIVATIVE; ETHYLAMINE; PHOSPHINE OXIDE DERIVATIVE; SILANE DERIVATIVE; TETRABUTYLAMMONIUM;

ALLYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; ENANTIOSELECTIVITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

EID: 9944259566     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.10.168     Document Type: Article

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22. 6)) as a colorless oil. Ee was determined to be 43% by chiral HPLC (Daicel Chiralcel OD, 1 mL/min, hexane/2-propanol = 40:1)