Fluorinated models of the iron-only hydrogenase: An electrochemical study of the influence of an electron-withdrawing bridge on the proton reduction overpotential and catalyst stability

Journal of Electroanalytical Chemistry

Volumn 703, Issue , 2013, Pages 14-22

  Ridley, Faith ^a   Ghosh, Shishir ^a   Hogarth, Graeme ^a   Hollingsworth, Nathan ^a   Holt, Katherine B ^a   Unwin, David G ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

Di iron complexes; Electrocatalysis; Fluorinated thiolate; Hydrogenases; Phosphines; Proton reduction

Indexed keywords

CATALYSIS; COORDINATION REACTIONS; ELECTROCATALYSIS; ELECTROCHEMISTRY; ELECTROLYTIC REDUCTION; IRON; PHOSPHORUS COMPOUNDS; PROTONATION; PROTONS;

DIIRON COMPLEX; HYDROGENASES; PHOSPHINES; PROTON REDUCTION; THIOLATES;

IRON COMPOUNDS;

EID: 84879237712     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2013.05.018     Document Type: Article

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