A carbonyl-rich bridging hydride complex relevant to the Fe-Fe hydrogenase active site

Inorganic Chemistry

Volumn 49, Issue 21, 2010, Pages 9746-9748

  Matthews, Steven L ^a   Heinekey, D Michael ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FERROUS ION; HYDROCHLORIC ACID; HYDROGENASE; IRON HYDROGENASE; IRON SULFUR PROTEIN; PROTON;

ARTICLE; BIOCATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; DIMERIZATION; ENZYME ACTIVE SITE; METABOLISM; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

BIOCATALYSIS; CATALYTIC DOMAIN; CRYSTALLOGRAPHY, X-RAY; DIMERIZATION; FERROUS COMPOUNDS; HYDROCHLORIC ACID; HYDROGENASE; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PROTONS; STEREOISOMERISM;

EID: 78049274272     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic1017328     Document Type: Article

References (29)

1. Peters, J. W., Lanzilotta, W. N., Lemon, B. J., and Seefeldt, L. C. Science 1998, 282, 1853
2. Nicolet, Y., Piras, C., Legrand, C. P., Hatchikian, C. E., and Fontecilla-Camps, J. C. Structure 1999, 7, 13
3. Alper, J. Science 2003, 299, 1688
4. Kubas, G. J. J. Organomet. Chem. 2009, 694, 2648
5. Gloaguen, F. and Rauchfuss, T. B. Chem. Soc. Rev. 2009, 38, 100
6. Liu, T. and Darensbourg, M. Y. J. Am. Chem. Soc. 2007, 129, 7008
7. Justice, A. K., Rauchfuss, T. B., and Wilson, S. R. Angew. Chem. 2007, 46, 6152
8. Capon, J.-F., Gloaquen, F., Schollhamer, P., and Talarmin, J. Coord. Chem. Rev. 2005, 249, 1664
9. Savariault, J.-M., Bonnet, J.-J., Mathieu, R., and Galy, J. C. R. Acad. Sci. Paris 1977, 284, C 663
10. Zhao, X., Georgakaki, I. P., Miller, M. L., Yarbrough, J. C., and Darensbourg, M. Y. J. Am. Chem. Soc. 2001, 123, 9710
11. Wright, J. A. and Pickett, C. J. Chem. Commun. 2009, 5719
12. Zhao, X., Chiang, C.-Y., Miller, M. L., Rampersad, M. V., and Darensbourg, M. Y. J. Am. Chem. Soc. 2003, 125, 518
13. Nehring, J. L. and Heinekey, D. M. Inorg. Chem. 2003, 42, 4288
14. Garcia, I. A. C. Ph.D. Dissertation, University of Washington, Seattle, WA, 2007.
15. Lambert, J. B., Zhang, S., and Ciro, S. M. Organometallics 1994, 13, 2430
16. Avelar, A., Tham, F. S., and Reed, C. A. Angew. Chem. 2009, 48, 3491
17. Reed, C. A., Fackler, N. L. P., Kim, K.-C., Stasko, D., and Evans, D. R. J. Am. Chem. Soc. 1999, 121, 6314
18. 5F): δ 1.66 (4H, t), 1.34 (2H, quint)
19. We have been unable to prepare a sample of 2 for IR analysis free of traces of 1 because of extremely facile deprotonation.
20. Hwang, T.-L. and Shaka, A. J. J. Magn. Reson. A 1995, 112, 275
21. Rosenthal, J. and Schuster, D. I. J. Chem. Educ. 2003, 80, 679
22. a of protonated benzene is -9.2 in anhydrous HF. See: Reutov, O. A., Beletskaya, I. P., and Butin, K. P. CH acids; Pergamon Press: New York, 1978.
23. Lyon, E. J., Georgakaki, I. P., Reibenspeis, J. H., and Darensbourg, M. Y. Angew. Chem., Int. Ed. 1999, 38, 3178
24. Li, P., Wang, M., Chen, L., Liu, J., Zhao, Z., and Sun, L. Dalton Trans. 2009, 1919
25. Morvan, D., Capon, J.-F., Gloagen, F., Petillon, F. Y., Schollhammer, P., Talarmin, J., Yaouanc, J.-J., Michaud, F., and Kervarec, N. J. Organomet. Chem. 2009, 694, 2801
26. Zhao, X., Georgakaki, I. P., Miller, M. L., Rodriguez, R. M., Chiang, C.-Y., and Darensbourg, M. Y. Inorg. Chem. 2002, 41, 3917
27. Rauchfuss, T. B., Contakes, S. M., Hsu, C. N., Reynolds, M. A., and Wilson, S. R. J. Am. Chem. Soc. 2001, 123, 6933
28. Hardman, N. J., Fang, X., Scott, B. L., Wright, R. J., Martin, R. L., and Kubas, G. J. Inorg. Chem. 2005, 44, 8306
29. Charley, L. M. and Angelici, R. J. Inorg. Chem. 1971, 10, 868