One- to two-electron reduction of an [FeFe]-hydrogenase active site mimic: The critical role of fluxionality of the [2Fe2S] core

Journal of the American Chemical Society

Volumn 131, Issue 32, 2009, Pages 11290-11291

  Felton, Greg A N ^a   Petro, Benjamin J ^a   Glass, Richard S ^a   Lichtenberger, Dennis L ^a   Evans, Dennis H ^a  

^a University of Arizona   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; CARBONYL LIGAND; COMPLEX ANIONS; DIANIONS; ELECTROCHEMICAL CONDITIONS; FLUXIONALITY; HYDROGENASES; IRON CENTERS; IRON-SULFUR CLUSTERS; NEGATIVE POTENTIAL; ONE-ELECTRON REDUCTIONS; SCAN RATES; STRUCTURAL REARRANGEMENT; TWO-ELECTRON REDUCTION;

ELECTRONS; NEGATIVE IONS; SULFUR;

REDUCTION;

ANION; CARBONYL DERIVATIVE; FERREDOXIN; HYDROGENASE; IRON; SULFUR;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; ELECTROCHEMISTRY; ELECTRON; ELECTRON TRANSPORT; REACTION ANALYSIS; REDUCTION; TEMPERATURE;

BIOMIMETICS; CATALYSIS; CATALYTIC DOMAIN; ELECTROCHEMICAL TECHNIQUES; ELECTRONS; FERROUS COMPOUNDS; HYDROGENASE; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; OXIDATION-REDUCTION;

EID: 68849087997     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja904520x     Document Type: Article

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