First generation analogues of the binuclear site in the Fe-only hydrogenases: Fe2(μ-SR)2(CO)4(CN)2/2-[8]

Journal of the American Chemical Society

Volumn 121, Issue 41, 1999, Pages 9736-9737

  Schmidt, Michael ^a   Contakes, Stephen M ^a   Rauchfuss, Thomas B ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BACTERIAL ENZYME; CYANIDE; IRON COMPLEX; OXIDOREDUCTASE;

CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CONTROLLED STUDY; CRYSTALLIZATION; CRYSTALLOGRAPHY; DESULFOVIBRIO; ENZYME ACTIVE SITE; ENZYME STRUCTURE; LETTER; METAL BINDING; NONHUMAN; STOICHIOMETRY;

EID: 0032703723     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9924187     Document Type: Letter

References (22)

1. Cammack, R. Nature 1999, 397, 214-215.
2. Adams, M. W. W. FEMS Microbiol. Rev. 1994, 15, 261-277.
3. Adams, M. W. W.; Stiefel, E. I. Science 1998, 282, 1842-1843.
4. Volbeda, A.; Charan, M.-H.; Piras, C.; Hatchikian, E. C.; Frey, M.; Fontecilla-Camps, J. C. Nature 1995, 373, 580-587.
5. Lai, C-H.; Lee, W.-Z.; Miller, M. L.; Reibenspies, J. H.; Darensbourg, D. J.; Darensbourg, M. Y. J. Am. Chem. Soc. 1998, 120, 10103-10114.
6. Amara, P.; Volbeda, A.; Carlos, J. C.; Fontecilla-Camps, J. C.; Field, M. J. J. Am. Chem. Soc. 1999, 121, 4468-4477.
7. Nicolet, Y.; Piras, C.; Legrand, P.; Halchikian, C. E.; Fontecilla-Camps, J. C. Structure 1999, 7, 13-23.
8. Peters, J. W.; Lanzilotta, W. N.; Lemon, B. J.; Seefeldt, L. C. Science 1998, 252, 1853-1858.
9. King, R. B. J. Am. Chem. Soc. 1962, 84, 2460.
10. 2 (Found): C, 27.02 (27.15); H, 2.00 (1.89); N, 7.00 (7.26).
11. IR study of the D. vulgaris Fe hydrogenase: Pierik, A. J.; Hulstein, M.; Hagen, W. R.; Albracht, S. P. J. Eur. J. Biochem. 1998, 258, 572-578.
12. Crystallographic details for 1b: space group P1 (Z = 2); a = 10.7271(8), b = 12.9116(10), and c = 21.1722(16) Å, a = 80.023(2), β = 79.553(2), and γ = 71.198(2)°.
13. Seyferth, D.; Henderson, R. S.; Song, L. C. Organometallics 1982, 1, 125-133.
14. Lilley, G. L.; Sinn, E.; Averill, B. A. Inorg. Chem. 1986, 25, 1073-1075.
15. Winter, A.; Zsolnai, L.; Huttner, G. Z. Naturforsch. 1982, 37b, 1430-1436.
16. 2 = 0.1592; GOF = 0.976.
17. Dahl, L. F.; Wei, C. H. Inorg. Chem. 1963, 2, 328-334.
18. Hsu, H.-F.; Koch, S. A.; Popescu, C. V.; Münck, E. J. Am. Chem. Soc. 1997, 119, 8371-8372.
19. Haines, R. J.; de Beer, J. A.; Greatrex, R. J. Chem. Soc., Dalton Trans. 1976, 1749-1757.
20. Dunbar, K. R.; Heitz, R. A. Prog. Inorg. Chem. 1997, 45, 283-391.
21. Nakamoto, K. Infrared and Roman Spectra of Inorganic and Coordination Compounds; John Wiley: New York, 1986.
22. Thauer, R. K.; Klein, A. R.; Hartmann, G. C. Chem. Rev. 1996, 96, 3031-3042.