Catalytic hydrogen evolution from mononuclear iron(II) carbonyl complexes as minimal functional models of the [FeFe] hydrogenase active site

Angewandte Chemie - International Edition

Volumn 49, Issue 43, 2010, Pages 8033-8036

  Kaur Ghumaan, Sandeep ^a   Schwartz, Lennart ^a   Lomoth, Reiner ^a   Stein, Matthias ^b,c   Ott, Sascha ^a  

^a UPPSALA UNIVERSITY   (Sweden)

^b HEIDELBERG INSTITUTE FOR THEORETICAL STUDIES   (Germany)

^c MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

Author keywords

Bioinorganic chemistry; Enzyme catalysis; Hydrogen production; Hydrogenases; Iron complexes

Indexed keywords

[FEFE]HYDROGENASES; ACTIVE SITE; BIOINORGANIC CHEMISTRY; CARBONYL COMPLEXES; CATALYTIC HYDROGEN EVOLUTION; COORDINATION SITES; DFT CALCULATION; ELECTROCHEMICAL REDUCTIONS; ENZYME CATALYSIS; FUNCTIONAL MODEL; HYDROGENASES; IRON COMPLEXES; MONONUCLEAR COMPLEXES; PROTONATED; SULFUR LIGANDS;

BIOCHEMISTRY; CATALYSIS; ELECTROLYTIC REDUCTION; ENZYMES; GAS PRODUCERS; IRON COMPOUNDS; SULFUR; SULFUR COMPOUNDS;

HYDROGEN PRODUCTION;

FERROUS ION; HYDROGEN; HYDROGENASE; PROTON;

ARTICLE; BIOMIMETICS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; ENZYME ACTIVE SITE;

BIOMIMETICS; CATALYSIS; CATALYTIC DOMAIN; FERROUS COMPOUNDS; HYDROGEN; HYDROGENASE; MODELS, MOLECULAR; PROTONS;

EID: 78349283055     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201002719     Document Type: Article

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