Enantioselective synthesis of α-tri- and α-tetrasubstituted allylsilanes by copper-catalyzed asymmetric allylic substitution of allyl phosphates with silylboronates

Journal of Organic Chemistry

Volumn 78, Issue 10, 2013, Pages 5007-5017

  Takeda, Momotaro ^a   Shintani, Ryo ^a,b   Hayashi, Tamio ^c,d  

^a KYOTO UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c INSTITUTE OF MATERIALS RESEARCH AND ENGINEERING   (Singapore)

^d NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC SUBSTITUTION; ALLYLSILANES; CATALYST SYSTEM; ENANTIOSELECTIVE SYNTHESIS;

ALLYLATION; CATALYSIS; ORGANIC COMPOUNDS; SUBSTITUTION REACTIONS;

PHOSPHATES;

ALLYL CHLORIDE; BORONIC ACID DERIVATIVE; CARBENE; COPPER; ELECTROPHILE; PHOSPHATE;

ALLYLIC REARRANGEMENT; ARTICLE; CATALYSIS; CHIRALITY; ENANTIOSELECTIVITY; HYDROBORATION; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS;

BORONIC ACIDS; CATALYSIS; COPPER; MOLECULAR STRUCTURE; ORGANOPHOSPHATES; SILANES; STEREOISOMERISM;

EID: 84878028009     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo400888b     Document Type: Article

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