Intramolecular general base catalysis in the hydrolysis of a phosphate diester. calculational guidance to a choice of mechanism

Journal of Organic Chemistry

Volumn 78, Issue 4, 2013, Pages 1343-1353

  Kirby, Anthony J ^a   Medeiros, Michelle ^b   Mora, José R ^b   Oliveira, Pedro S M ^b   Amer, Almahdi ^c   Williams, Nicholas H ^c   Nome, Faruk ^b  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

^c UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

DIESTERS; GENERAL BASE; INTRAMOLECULAR CATALYSIS; INTRAMOLECULAR GENERAL BASE CATALYSIS; LEAVING GROUPS; MINIMAL EFFECTS; MOLARITY; NEW RESULTS; NONLEAVING GROUPS; ORDERS OF MAGNITUDE; POSSIBLE MECHANISMS; PYRIDINE NITROGEN; RATE OF HYDROLYSIS; SINGLE-STEP; SPONTANEOUS HYDROLYSIS; TRIESTERS;

HYDROLYSIS; NITROGEN;

CATALYSIS;

NITROGEN; ORGANOPHOSPHATE; PYRIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL BOND; HALF LIFE TIME; HYDROLYSIS; IONIC STRENGTH; MOLECULAR MECHANICS; PH; PROTON TRANSPORT; THERMODYNAMICS;

CATALYSIS; ESTERS; HYDROGEN-ION CONCENTRATION; HYDROLYSIS; KINETICS; MOLECULAR STRUCTURE; ORGANOPHOSPHATES; PYRIDINES; TEMPERATURE; WATER;

EID: 84873944607     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo302498g     Document Type: Article

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