Activating water: Important effects of non-leaving groups on the hydrolysis of phosphate triesters

Chemistry - A European Journal

Volumn 17, Issue 52, 2011, Pages 14996-15004

  Kirby, Anthony J ^a   Medeiros, Michelle ^b   Oliveira, Pedro S M ^b   Orth, Elisa S ^b   Brandão, Tiago A S ^b   Wanderlind, Eduardo H ^b   Amer, Almahdi ^c   Williams, Nicholas H ^c   Nome, Faruk ^b  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

^c UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

basicity; hydrolysis; intramolecular catalysis; kinetics; phosphorus

Indexed keywords

HIGH RATE; INTRAMOLECULAR CATALYSIS; LEAVING GROUPS; PYRIDINE NITROGEN; RATE MEASUREMENTS; SPONTANEOUS HYDROLYSIS; TRIESTERS;

ALKALINITY; CATALYSIS; ENZYME KINETICS; NUCLEOPHILES; PHOSPHORUS;

HYDROLYSIS;

ORGANOPHOSPHATE; PYRIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HYDROLYSIS; KINETICS; PH;

CATALYSIS; HYDROGEN-ION CONCENTRATION; HYDROLYSIS; KINETICS; MOLECULAR STRUCTURE; PHOSPHORIC ACID ESTERS; PYRIDINES;

EID: 83755219929     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201101926     Document Type: Article

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